Sm(5-bromosalicylidene-4-amino-3-mercapto-1,2,4-triazine-5-one)(ONO2)(H2O)2 | 1374160-51-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三唑并哒嗪类
• 英文名称: Sm(5-bromosalicylidene-4-amino-3-mercapto-1,2,4-triazine-5-one)(ONO2)(H2O)2
• CAS: 1374160-51-6
• 化学式: C₁₀H₉BrN₅O₇SSm
• 分子量: 573.541
• InChiKey: HSETZASCDQUKSJ-NZYHXYHESA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Sm(5-bromosalicylidene-4-amino-3-mercapto-1,2,4-triazine-5-one)(ONO2)(H2O)2 以 neat (no solvent, solid phase) 为溶剂， 生成 samarium(III) oxide
  参考文献：
  名称：

  Thermal and Antibacterial Studies of Novel Lanthanide–Schiff Base Complexes

  摘要：

  Novel lanthanide complexes with the general formula [Ln(L)(ONO2)(H2O)(2)] have been synthesized and characterized. {L = 5-bromosalicylidene 4-amino 3-mercapto-1,2,4-triazine-5-one (BrSAMT), Ln = La(III), Ce(III), (Pr(III) Eu(III), Sm(III), Nd(III), Tb(III), Dy(III), and Y(III)}. The thermal, magnetic, molar conductance, and spectral studies confirm that the ligand coordinates through sulfur, azomethine nitrogen, and phenolic oxygen. A scheme of thermal decomposition of the complexes is also proposed. La, Eu, and Yb complexes of BrSAMT show antibacterial activity against gram negative bacteria such as E. coli, Pseudomonas aeruginosa, Salmonella typhi, and Shigella flexneri.

  DOI：

  10.1080/15533174.2011.613883
• 作为产物：
  描述：

  5-bromosalicylidene-4-amino-3-mercapto-1,2,4-triazine-5-one 、 水 、 samarium(III) nitrate 以 乙醇 为溶剂， 生成 Sm(5-bromosalicylidene-4-amino-3-mercapto-1,2,4-triazine-5-one)(ONO2)(H2O)2
  参考文献：
  名称：

  Thermal and Antibacterial Studies of Novel Lanthanide–Schiff Base Complexes

  摘要：

  Novel lanthanide complexes with the general formula [Ln(L)(ONO2)(H2O)(2)] have been synthesized and characterized. {L = 5-bromosalicylidene 4-amino 3-mercapto-1,2,4-triazine-5-one (BrSAMT), Ln = La(III), Ce(III), (Pr(III) Eu(III), Sm(III), Nd(III), Tb(III), Dy(III), and Y(III)}. The thermal, magnetic, molar conductance, and spectral studies confirm that the ligand coordinates through sulfur, azomethine nitrogen, and phenolic oxygen. A scheme of thermal decomposition of the complexes is also proposed. La, Eu, and Yb complexes of BrSAMT show antibacterial activity against gram negative bacteria such as E. coli, Pseudomonas aeruginosa, Salmonella typhi, and Shigella flexneri.

  DOI：

  10.1080/15533174.2011.613883