1-{3-[4'-(3-Propynoyl-phenoxymethyl)-biphenyl-4-ylmethoxy]-phenyl}-propynone | 302919-96-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-{3-[4'-(3-Propynoyl-phenoxymethyl)-biphenyl-4-ylmethoxy]-phenyl}-propynone
• CAS: 302919-96-6
• 化学式: C₃₂H₂₂O₄
• 分子量: 470.524
• InChiKey: HLZQJNQWFUJNGL-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  1-{3-[4'-(3-Propynoyl-phenoxymethyl)-biphenyl-4-ylmethoxy]-phenyl}-propynone 在 potassium carbonate 作用下， 以 甲苯 为溶剂， 反应 12.0h， 生成 [3-(4'-{3-[3,5-Bis-(3-nitro-benzoyl)-benzoyl]-phenoxymethyl}-biphenyl-4-ylmethoxy)-phenyl]-[3,5-bis-(3-nitro-benzoyl)-phenyl]-methanone
  参考文献：
  名称：

  Synthesis of linked 1,3,5-triaroylbenzenes via enamine-directed alkyne cyclotrimerization

  摘要：

  Triaroylbenzenes connected via m-xylyl, p-xylyl, 4,4'-biphenyl, and 1,3,5-benzenetriyl linking units have been prepared in good yield by condensation of bis(enaminones) with aryl ethynyl ketones, The required bis(enaminones) were conveniently prepared starting from the corresponding bis- or tris(halomethyl) linking units and 3-hydroxybenzaldehyde. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)01125-4
• 作为产物：
  描述：

  1-(3-{4'-[3-(1-Hydroxy-prop-2-ynyl)-phenoxymethyl]-biphenyl-4-ylmethoxy}-phenyl)-prop-2-yn-1-ol 在 jones reagent 作用下， 生成 1-{3-[4'-(3-Propynoyl-phenoxymethyl)-biphenyl-4-ylmethoxy]-phenyl}-propynone
  参考文献：
  名称：

  Synthesis of linked 1,3,5-triaroylbenzenes via enamine-directed alkyne cyclotrimerization

  摘要：

  Triaroylbenzenes connected via m-xylyl, p-xylyl, 4,4'-biphenyl, and 1,3,5-benzenetriyl linking units have been prepared in good yield by condensation of bis(enaminones) with aryl ethynyl ketones, The required bis(enaminones) were conveniently prepared starting from the corresponding bis- or tris(halomethyl) linking units and 3-hydroxybenzaldehyde. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)01125-4