trans-[ReO(NCS)2(OEt)(PPh3)2] | 277743-01-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-[ReO(NCS)2(OEt)(PPh3)2]
• CAS: 277743-01-8
• 化学式: C₄₀H₃₅N₂O₂P₂ReS₂
• 分子量: 888.017
• InChiKey: MBKABZKPMASXOS-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  trans-[ReOI₂(OEt)(PPh₃)₂] 、 sodium thiocyanide 以 乙醇 为溶剂， 生成 trans-[ReO(NCS)2(OEt)(PPh3)2]
  参考文献：
  名称：

  Structure of trans-diisothiocyanato(ethoxo)oxo-bis(triphenylphosphine)rhenium(V) complex

  摘要：

  The title compound consists of [ReO(NCS)(2)(OEt)(PPh3)(2)] units in which the rhenium(V) center shows a slightly distorted octahedral coordination. The two N-coordinated NCS- groups are trans to each other, as the Re=O and the Re-Oft units. The Re=O and Re-OEt bond lengths [1.682(10) and 1.871(10) Angstrom, respectively] and the geometry about the ethoxide oxygen atom indicate that in both cases M-O ligation has a considerable degree of multiple bond. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00057-8