ETE-Lum | 1175664-79-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: ETE-Lum
• 英文别名: 5,7-Bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2,3-dihydrothieno[3,4-d]pyridazine-1,4-dione；5,7-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2,3-dihydrothieno[3,4-d]pyridazine-1,4-dione
• CAS: 1175664-79-5
• 化学式: C₁₈H₁₂N₂O₆S₃
• 分子量: 448.501
• InChiKey: CPXVMOWOIVPURZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  29
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  180
• 氢给体数：
  2
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  diethyl 2,5-di(3,4-ethylenedioxythiophen-2-yl)thiophene-3,4-dicarboxylate 在 水 、 肼 作用下， 以 甲醇 为溶剂， 以36%的产率得到ETE-Lum
  参考文献：
  名称：

  Synthesis and properties of a novel redox driven chemiluminescent material built on a terthienyl system

  摘要：

  A novel redox driven chemiluminescent material built on a terthienyl system, namely 5,7-di-ethylenedioxythiophen-2-yl-2,3-dihydro-thieno[3,4-d]pyridazine-1,4-dione (ETE-Lum), which is soluble in both organic media and basic aqueous solution was synthesized and characterized. Furthermore, its polymer, PETE-Lum, which is one of the most rare examples of chemiluminescent polymeric materials bearing a pyridazine unit, was obtained successfully by electrochemical means. Both of the materials give chemiluminescence either by treatment with oxidants (H2O2 and/or KMnO4) or by the application of a potential pulse. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.05.019

文献信息

• Synthesis and properties of a novel redox driven chemiluminescent material built on a terthienyl system
  作者：Nurdan Atılgan、Fatih Algı、Ahmet M. Önal、Atilla Cihaner

  DOI：10.1016/j.tet.2009.05.019

  日期：2009.7

  A novel redox driven chemiluminescent material built on a terthienyl system, namely 5,7-di-ethylenedioxythiophen-2-yl-2,3-dihydro-thieno[3,4-d]pyridazine-1,4-dione (ETE-Lum), which is soluble in both organic media and basic aqueous solution was synthesized and characterized. Furthermore, its polymer, PETE-Lum, which is one of the most rare examples of chemiluminescent polymeric materials bearing a pyridazine unit, was obtained successfully by electrochemical means. Both of the materials give chemiluminescence either by treatment with oxidants (H2O2 and/or KMnO4) or by the application of a potential pulse. (C) 2009 Elsevier Ltd. All rights reserved.