bis(n-butylamine)(phthalocyaninato)ruthenium | 199666-77-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: bis(n-butylamine)(phthalocyaninato)ruthenium
• CAS: 199666-77-8
• 化学式: C₄₀H₃₈N₁₀Ru
• 分子量: 759.879
• InChiKey: GBTWBNOVEBHWDI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (phthalocyaninato)ruthenium 、 正丁胺 以 氯仿 为溶剂， 以58%的产率得到bis(n-butylamine)(phthalocyaninato)ruthenium
  参考文献：
  名称：

  Structural Investigations of Ruthenium Phthalocyanines with EXAFS Spectroscopy

  摘要：

  To obtain a more detailed insight into the structure of PcRu (1), an EXAFS investigation has been carried out on amorphous PcRu and compared with the bisubstituted PcRu(n-BuNH2)(2) (2). From the obtained atomic distances around the metal center, it was possible to deduce detailed structural models for both compounds. For 1, the dimeric structure was confirmed; for 2, the EXAFS measurements led to an unusual structure in which both n-butylamine:groups are located on one side of the PcRu ring.

  DOI：

  10.1021/ic970653p