| 335248-30-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 335248-30-1
• 化学式: C₄H₈O*C₁₉H₂₃Cl₄N₃Zr
• 分子量: 600.533
• InChiKey: SRSSQRBIDRNOHU-MOVGKGBASA-N

反应信息

• 作为反应物：
  描述：

  、 N,N-二甲基苯铵四(五氟苯基)硼酸盐 以 further solvent(s) 为溶剂， 生成
  参考文献：
  名称：

  CH Bond Activation in Cations of the Type {[(2,4,6-Me₃C₆H₂NCH₂CH₂)₂NMe]ZrR}⁺ and a Simple Solution that Yields a Catalyst for the Living Polymerization of 1-Hexene

  摘要：

  {[(MesNCH(2)CH(2))(2)NMe]ZrMe}[B(C6F5)(4)] and intermediates in the polymerization reaction of 1-hexene that are formed from it decompose as a consequence of CH activation in an ortho methyl group in the mesityl substituent. The intermediates in the polymerization reaction decompose significantly more readily than does {[(MesrNCH(2)CH(2))(2)NMe]ZrMe }[B(C6F5)(4)] On the other hand, analogous cationic complexes that contain the [(2,6-Cl2C6H3NCH2 CH2)(2)NMe](2-) ligand a re re la ti very stable and will consume 1-hexene in a strictly first-order and apparently living manner at 0 degreesC in chlorobenzene.

  DOI：

  10.1021/om000972f