| 873313-40-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 873313-40-7
• 化学式: C₈₉H₅₆Co₂N₁₀O
• 分子量: 1399.48
• InChiKey: HIDUMMGGADZBQO-VVKHVWBYSA-M

反应信息

• 作为反应物：
  描述：

  在 air 作用下， 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Dicobalt diporphyrin complex with hyperfine EPR spectrum mediates only a two-electron reduction of O2

  摘要：

  A dicobalt diporphyrin complex can form mu-superoxo dimer with O-2 in chloroform in the absence of organic base to give 15-line highly symmetrical EPR spectrum. This complex can only catalyze 02 reduction by a two-electron pathway, suggesting that there is no correlation between the shape of the CO-O-2-Co EPR signal and the electrocatalytical ability of dicobalt diporphyrin complexs to mediate the four-electron reduction of O-2. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.06.004
• 作为产物：
  描述：

  、 cobalt(II) acetate 以 丙酸 为溶剂， 生成
  参考文献：
  名称：

  Dicobalt diporphyrin complex with hyperfine EPR spectrum mediates only a two-electron reduction of O2

  摘要：

  A dicobalt diporphyrin complex can form mu-superoxo dimer with O-2 in chloroform in the absence of organic base to give 15-line highly symmetrical EPR spectrum. This complex can only catalyze 02 reduction by a two-electron pathway, suggesting that there is no correlation between the shape of the CO-O-2-Co EPR signal and the electrocatalytical ability of dicobalt diporphyrin complexs to mediate the four-electron reduction of O-2. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.06.004