N-(2,5-dibromo-1-phenyl-1lambda5-phosphol-1-ylidene)butane-1-sulfonamide | 1421342-98-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(2,5-dibromo-1-phenyl-1lambda5-phosphol-1-ylidene)butane-1-sulfonamide
• 英文别名: N-(2,5-dibromo-1-phenyl-1λ5-phosphol-1-ylidene)butane-1-sulfonamide
• CAS: 1421342-98-4
• 化学式: C₁₄H₁₆Br₂NO₂PS
• 分子量: 453.134
• InChiKey: VREDUNMBANELBP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  21
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  54.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  在 N-溴代丁二酰亚胺(NBS) 作用下， 以 氯仿 为溶剂， 以15%的产率得到N-(2,5-dibromo-1-phenyl-1lambda5-phosphol-1-ylidene)butane-1-sulfonamide
  参考文献：
  名称：

  Synthesis and Charge-Carrier Transport Properties of Poly(phosphole P-alkanesulfonylimide)s

  摘要：

  A new class of polyphospholes bearing alkanesulfonylimino moieties on the phosphorus(V) centers was prepared by the Pd-Cul-promoted Stille coupling reaction to investigate the charge-carrier transport properties of the pi-networks of polyphospholes. Time-of-flight measurements have revealed that the poly(phosphole P-imide)s possess ambipolar charge-carrier mobilities of up to mu(electron) = 6 x 10(-3) cm(2) V-1 s(-1) and mu(hole) = 4 x 10(-3) cm(2) V-1 s(-1).

  DOI：

  10.1021/ol4000982

文献信息

• Synthesis and Charge-Carrier Transport Properties of Poly(phosphole <i>P</i>-alkanesulfonylimide)s
  作者：Yoshihiro Matano、Hiroshi Ohkubo、Yoshihito Honsho、Arihiro Saito、Shu Seki、Hiroshi Imahori

  DOI：10.1021/ol4000982

  日期：2013.2.15

  A new class of polyphospholes bearing alkanesulfonylimino moieties on the phosphorus(V) centers was prepared by the Pd-Cul-promoted Stille coupling reaction to investigate the charge-carrier transport properties of the pi-networks of polyphospholes. Time-of-flight measurements have revealed that the poly(phosphole P-imide)s possess ambipolar charge-carrier mobilities of up to mu(electron) = 6 x 10(-3) cm(2) V-1 s(-1) and mu(hole) = 4 x 10(-3) cm(2) V-1 s(-1).