2-[3-[3-[4-[Bis[3-[bis[3-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]propyl]amino]propyl]amino]butyl-[3-[bis[3-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]propyl]amino]propyl]amino]propyl-[3-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]propyl]amino]propyliminomethyl]-4,6-ditert-butylphenol | 1415347-61-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[3-[3-[4-[Bis[3-[bis[3-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]propyl]amino]propyl]amino]butyl-[3-[bis[3-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]propyl]amino]propyl]amino]propyl-[3-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]propyl]amino]propyliminomethyl]-4,6-ditert-butylphenol
• 英文别名: 2-[3-[3-[4-[bis[3-[bis[3-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]propyl]amino]propyl]amino]butyl-[3-[bis[3-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]propyl]amino]propyl]amino]propyl-[3-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]propyl]amino]propyliminomethyl]-4,6-ditert-butylphenol
• CAS: 1415347-61-3
• 化学式: C₁₆₀H₂₅₆N₁₄O₈
• 分子量: 2503.88
• InChiKey: CCFSGBVMRMWKPM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  39.5
• 重原子数：
  182
• 可旋转键数：
  77
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  280
• 氢给体数：
  8
• 氢受体数：
  22

反应信息

• 作为反应物：
  描述：

  2-[3-[3-[4-[Bis[3-[bis[3-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]propyl]amino]propyl]amino]butyl-[3-[bis[3-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]propyl]amino]propyl]amino]propyl-[3-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]propyl]amino]propyliminomethyl]-4,6-ditert-butylphenol 、 cobalt(II) diacetate tetrahydrate 在 sodium hydroxide 作用下， 以 甲醇 为溶剂， 反应 4.0h， 以70%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of dendritic salicylaldimine complexes of copper and cobalt and their use as catalyst precursors in the aerobic hydroxylation of phenol

  摘要：

  A series of generation 1 (G1) and generation 2 (G2) salicylaldimine functionalized polypropylene imine dendrimers were used to prepare a range of new copper and cobalt metallodendrimers. These were found to be efficient catalysts in the aerobic hydroxylation of phenol using H2O2 and molecular oxygen as oxidants. The major products obtained were catechol and hydroquinone. The selectivity to these two products was greatly influenced by the nature of the metallodendrimer as well as by the pH of the reaction medium. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.09.006

文献信息

• Synthesis and characterization of dendritic salicylaldimine complexes of copper and cobalt and their use as catalyst precursors in the aerobic hydroxylation of phenol
  作者：S.F. Mapolie、J.L. van Wyk

  DOI：10.1016/j.ica.2012.09.006

  日期：2013.1

  A series of generation 1 (G1) and generation 2 (G2) salicylaldimine functionalized polypropylene imine dendrimers were used to prepare a range of new copper and cobalt metallodendrimers. These were found to be efficient catalysts in the aerobic hydroxylation of phenol using H2O2 and molecular oxygen as oxidants. The major products obtained were catechol and hydroquinone. The selectivity to these two products was greatly influenced by the nature of the metallodendrimer as well as by the pH of the reaction medium. (C) 2012 Elsevier B. V. All rights reserved.