3-Vinyl-5-methyl-5-aethylhydantoin | 90197-35-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 英文名称: 3-Vinyl-5-methyl-5-aethylhydantoin
• 英文别名: 3-Ethenyl-5-ethyl-5-methylimidazolidine-2,4-dione
• CAS: 90197-35-6
• 化学式: C₈H₁₂N₂O₂
• 分子量: 168.195
• InChiKey: OWEMSDOUZVNMNX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  49.4
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• Composition and method for preparing linear copolymers of polar and non-polar olefins absent free radical addition polymer
  申请人：Rohm and Haas Company

  公开号：EP1964862A1

  公开（公告）日：2008-09-03

  A polynnerizable composition including a late transition metal complex, a non-polar olefin, a polar olefin, and a free radical scavenger, wherein the polymerizable composition is capable of forming a linear poly[(non-polar olefin)-(polar olefin)] substantially free of free radical addition polymer, is disclosed. A method of copolymerizing a non-polar olefin with a polar olefin, catalyzed by a late transition metal complex in the presence of a free radical scavenger, to produce a linear poly[(non-polar olefin)-(polar olefin)] substantially free of free radical addition polymer is also disclosed.

  本发明公开了一种可聚合组合物，该组合物包括晚过渡金属络合物、非极性烯烃、极性烯烃和自由基清除剂，其中该可聚合组合物能够形成基本上不含自由基加成聚合物的线性聚[（非极性烯烃）-（极性烯烃）]。本发明还公开了一种在游离基清除剂存在下，通过后期过渡金属配合物催化，使非极性烯烃与极性烯烃共聚，从而生成基本上不含游离基加成聚合物的线性聚[（非极性烯烃）-（极性烯烃）]的方法。
• A porous linear polymer composition
  申请人：Rohm and Haas Company

  公开号：EP1964859A1

  公开（公告）日：2008-09-03

  A porous polymer composition including plural linear mixed polarity polymer particles, wherein the particles include a linear poly[(non-polar olefin)-(polar olefin)] and at least one pore, is disclosed, as are those particles further including a catalytic component. A method of forming the plural linear mixed polarity polymer particles is also disclosed. A method of using plural linear mixed polarity polymer particles which include a catalytic component to catalyze polymerization is further disclosed. A porous polymer composition including plural linear non-polar polymer particles and a catalytic component is further disclosed, along with a method of making those linear non-polar polymer particles including the catalytic component and a method of using them to catalyze polymerization.

  本发明公开了一种多孔聚合物组合物，包括多个线性混合极性聚合物颗粒，其中颗粒包括线性聚[（非极性烯烃）-（极性烯烃）]和至少一个孔，这些颗粒还包括催化成分。还公开了一种形成复数线性混合极性聚合物颗粒的方法。还公开了一种使用包含催化成分的复数线性混合极性聚合物颗粒催化聚合的方法。进一步公开了一种包括复数线性非极性聚合物颗粒和催化组分的多孔聚合物组合物，以及制造这些包括催化组分的线性非极性聚合物颗粒的方法和使用它们催化聚合的方法。
• Substantially linear polymers and methods of making the same
  申请人：Rohm and Haas Company

  公开号：EP1964863A1

  公开（公告）日：2008-09-03

  Substantially linear copolymers derived from at least one acyclic aliphatic olefin monomer and at least one nitrogen containing vinyl monomer, wherein the at least one nitrogen containing vinyl monomer is according to Formula (I) wherein R19 is selected from -C=C, and -C(O)-C=C; wherein R20 and R21 are independently selected from H, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a biphenyl group, a carboxylate group, a carboxyalkyl group, a carboxyarylalkyl group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group, an alkoxycarbonyl group, and derivatives thereof. Also disclosed are methods of making such copolymers using late transition metal catalyst complexes.

  由至少一种无环脂肪族烯烃单体和至少一种含氮乙烯基单体衍生的基本线性共聚物，其中至少一种含氮乙烯基单体符合式 (I) 其中 R19 选自-C=C 和-C(O)-C=C；其中 R20 和 R21 独立选自 H、烷基、烯基、炔基、芳基、联苯基、羧酸基、羧基烷基、羧基芳烷基、烷氧基、烯氧基、炔氧基、芳氧基、烷氧羰基及其衍生物。还公开了使用后期过渡金属催化剂复合物制造此类共聚物的方法。
• CATALYST FOR SYNTHESIZING POLYOLEFINS
  申请人：The University of Tokyo

  公开号：EP2848623B1

  公开（公告）日：2017-09-27
• Composition and method for preparing linear copolymers of polar and non-polar olefins free of free radical initiated polymer
  申请人：Rohm and Haas Company

  公开号：EP1964862B1

  公开（公告）日：2010-12-22