bis((Bu)4methylenediphosphine)copper(II) chloride | 53189-20-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: bis((Bu)4methylenediphosphine)copper(II) chloride
• CAS: 53189-20-1
• 化学式: C₃₄H₇₆Cl₂CuO₄P₄
• 分子量: 807.322
• InChiKey: FTYFUAVSRSRFNT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 Tetrabutyl-methylen-diphosphin-dioxid 以 丙酮 、 甲苯 为溶剂， 生成 bis((Bu)4methylenediphosphine)copper(II) chloride 、 tris((Bu)4methylenediphosphine)copper(II) chloride 、 (Bu)4methylenediphosphine copper(II) chloride
  参考文献：
  名称：

  EPR of copper(II) chloride complexes with diphosphine dioxides

  摘要：

  Stepwise formation of copper(II) chloride complexes with diphosphine dioxides has been studied using paramagnetic resonance. It was found that in complexes with a copper:ligand composition of 1:1 substituents have little effect on parameters of the anisotropic EPR spectra. The spectra of complexes with a metal:ligand composition of 1:2 are considerably more sensitive to the introduction of substituents; this is explained by sterically dependent differences in the structure of the complexes. The possibility of trisligand complexes being formed is evidently largely determined by the size of the groups on the phosphorus atoms.

  DOI：

  10.1007/bf00965421