Hg(dpmp)I1 | 138496-44-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Hg(dpmp)I1
• CAS: 138496-44-3
• 化学式: C₃₂H₂₉HgI₂P₃
• 分子量: 960.903
• InChiKey: AUCRJSKLSPTBAA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  8.74
• 重原子数：
  38.0
• 可旋转键数：
  5.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  bis(diphenylphosphinomethyl)phenylphosphine 、 mercury(II) iodide 以 乙醇 、 二氯甲烷 为溶剂， 生成 Hg(dpmp)I1
  参考文献：
  名称：

  Mercury(II) complexes of bis(diphenylphosphinomethyl)phenylphosphine

  摘要：

  Treatment of mercury(II) chloride with dpmp (dpmp is bis(diphenylphosphinomethyl)phenylphosphine) yields a mixture of HgCl2(dpmp) and [Hg3(mu-Cl)2(mu-dpmp)2]Cl2. With mercury(II) bromide and iodide, only HgX2(dpmp) forms. [Hg3(mu-Cl2)Cl2(mu-dpmp)2]Cl(HCO3).5CHCl3 crystallizes in the monoclinic space group P2(1)/n with a = 16.424(5), b = 26.915(9), c = 19.896(5) angstrom, beta = 96.99(2)-degrees, at 130 K with Z = 4. Refinement of 434 parameters with 5277 reflections yields R = 0.080, R(w) = 0.067. The complex consists of three roughly tetrahedrally coordinated mercury ions that are connected to the two bridging phosphine ligands. Each mercury ion is coordinated to two phosphorus atoms and two chloride ligands. The Hg...Hg separations are 3.339(2) and 3.331(2) angstrom which suggest that there is little or no bonding between these d10 centers.

  DOI：

  10.1016/s0020-1693(00)90392-x