[bis(diphenylphosphino)methane-P,P']bis(nitrato-O)palladium(II) | 225663-61-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [bis(diphenylphosphino)methane-P,P']bis(nitrato-O)palladium(II)
• CAS: 225663-61-6
• 化学式: C₂₅H₂₂N₂O₆P₂Pd
• 分子量: 614.827
• InChiKey: ZXAOQTJSAWRLCT-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 silver nitrate 以 二氯甲烷 为溶剂， 以62%的产率得到[bis(diphenylphosphino)methane-P,P']bis(nitrato-O)palladium(II)
  参考文献：
  名称：

  [Bis(diphenylphosphino)methane]dinitratopalladium(II) tris(deuteriochloroform) solvate

  摘要：

  In the title compound, [methylenebis(diphenylphosphine-P)]bis(nitrato-O)palladium(II) tris(deuteriochloroform) solvate, [Pd(NO3)(2)(C25H22P2)]. 3CDCl(3) or [Pd(NO3)(2)(dppm)]. 3CDCl(3) [where dppm is bis(diphenylphosphino)methane], the PdO2P2 unit is planar, but the molecule is significantly distorted from ideal square-planar geometry. Principal dimensions include: Pd-P 2.2240(8) and 2.2345(7), Pd-O 2.103(2) and 2.130(2) Angstrom, P-Pd-P 72.52(3), O-Pd-O 85.23(9), and P-Pd-O 97.55(7) and 104.73(6)degrees. The CDCl3 molecules associate with the complex via C-D ... O hydrogen bonds.

  DOI：

  10.1107/s0108270198016345