(4-Bromophenyl)imino-oxo-phenyl-piperidin-1-yl-lambda6-sulfane | 1523524-09-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4-Bromophenyl)imino-oxo-phenyl-piperidin-1-yl-lambda6-sulfane
• 英文别名: (4-bromophenyl)imino-oxo-phenyl-piperidin-1-yl-λ6-sulfane
• CAS: 1523524-09-5
• 化学式: C₁₇H₁₉BrN₂OS
• 分子量: 379.321
• InChiKey: MUQOSNUPISZDDH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  41
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  tert-butyl (oxo(phenyl)(piperidin-1-yl)-λ⁶-sulfaneylidene)carbamate 在 copper diacetate 、 三氟乙酸 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 39.0h， 生成 (4-Bromophenyl)imino-oxo-phenyl-piperidin-1-yl-lambda6-sulfane
  参考文献：
  名称：

  A mild and efficient copper-catalyzed N-arylation of unprotected sulfonimidamides using boronic acids

  摘要：

  An efficient and low cost copper catalyzed system for N-arylation of sulfonimidamides has been developed. The reaction proceeds at room temperature under base free conditions. Various N-aryl, N-heteroaryl, and N-cyclopropyl sulfonimidamides were obtained in good to excellent yields. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.11.084

文献信息

• A mild and efficient copper-catalyzed N-arylation of unprotected sulfonimidamides using boronic acids
  作者：S.R.K. Battula、G.V. Subbareddy、I.E. Chakravarthy

  DOI：10.1016/j.tetlet.2013.11.084

  日期：2014.1

  An efficient and low cost copper catalyzed system for N-arylation of sulfonimidamides has been developed. The reaction proceeds at room temperature under base free conditions. Various N-aryl, N-heteroaryl, and N-cyclopropyl sulfonimidamides were obtained in good to excellent yields. (C) 2013 Elsevier Ltd. All rights reserved.