2,9,18,25-tetrathia-[10.10](2,6)-pyridinophane | 219972-12-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2,9,18,25-tetrathia-[10.10](2,6)-pyridinophane
• CAS: 219972-12-0
• 化学式: C₂₆H₃₈N₂S₄
• 分子量: 506.865
• InChiKey: RYYZNBZRWVJRHM-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 di(rhodium)tetracarbonyl dichloride 、 2,9,18,25-tetrathia-[10.10](2,6)-pyridinophane 以 甲醇 为溶剂， 以100%的产率得到
  参考文献：
  名称：

  Synthesis, coordination chemistry and crystal structures of [2+2] macrocycles incorporating 2,6-bis(thiomethyl)pyridine sub-units

  摘要：

  A series of potentially dinucleating [2 + 2] macrocyclic ligands with two SNS metal-binding domains separated by a variable polymethylene chain have been prepared. Two examples of these ligands have been structurally characterised. These ligands form polymeric adducts with [Rh-2(O2CCMe3)(4)] in which the ligands are thought to act as exocyclic S-donors to the axial sites of the dinuclear complex. In contrast, reaction with [(CO)(2)Rh(mu-Cl)(2)Rh(CO)(2)] resulted in the formation of dinuclear complexes in which two Rh(CO) units are bound to each macrocyclic ligand. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00238-1