uranyl 2,4,6-trimethylbenzenesulfonate trihydrate | 147101-20-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: uranyl 2,4,6-trimethylbenzenesulfonate trihydrate
• CAS: 147101-20-0
• 化学式: C₁₈H₂₈O₁₁S₂U
• 分子量: 722.575
• InChiKey: JIPTYBDBAVPPRS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  均三甲苯磺酸 、 uranyl acetate 在 H₂O 作用下， 以 水 为溶剂， 生成 uranyl 2,4,6-trimethylbenzenesulfonate trihydrate
  参考文献：
  名称：

  Crystal and molecular structures of sulfonato complexes of dioxouranium(VI) ion: Role of steric effects on coordination structure

  摘要：

  The crystal structures of three sulfonato complexes of uranyl ion are described. All have linear UO2 groups pentagonally coordinated by sulfonato or aquo ligands. In [(UO2)(H2O)(EtSO3)2] the coordination about UO2 is provided by four O donated by two EtSO3- ligands and one O by water: a sulfonate group links the pentagonal bipyramids into chains propagating along the a axis. p-Toluenesulfonato and mesitylenesulfonato complexes of uranyl ion are monomeric and in each complex two O are donated by monodentate sulfonate and three O by water molecules. The tendencies for complexes with small ligands to form polymeric structures, and for those with bulky ligands to give monomeric structures, which we have observed with carboxylate ligands, seem to extend to sulfonate ligands.

  DOI：

  10.1016/s0020-1693(00)82908-4