N,N'-dicyclohexyl-1-[2-[(N,N'-dicyclohexylcarbamimidoyl)-phenylphosphanyl]ethyl-phenylphosphanyl]methanimidamide | 890054-94-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-dicyclohexyl-1-[2-[(N,N'-dicyclohexylcarbamimidoyl)-phenylphosphanyl]ethyl-phenylphosphanyl]methanimidamide
• CAS: 890054-94-1
• 化学式: C₄₀H₆₀N₄P₂
• 分子量: 658.891
• InChiKey: LWTLEVQLGYTFGF-QWKHHPMFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  46
• 可旋转键数：
  13
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  48.8
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (1,5-cylooctadiene)di-iodoplatinum(II) 、 N,N'-dicyclohexyl-1-[2-[(N,N'-dicyclohexylcarbamimidoyl)-phenylphosphanyl]ethyl-phenylphosphanyl]methanimidamide 以 甲苯 为溶剂， 以29%的产率得到
  参考文献：
  名称：

  Coordination Chemistry of Isomeric Mixtures of Linked Di(phosphaguanidine) Compounds:  A Spectroscopic and Crystallographic Study

  摘要：

  Multinuclear NMR spectroscopy and X-ray diffraction techniques have been used to identify diastereomeric mixtures of rac- and meso-di(phosphaguanidine) compounds. A brief survey of their coordination chemistry has demonstrated the formation of N,N'-bound bimetallic aluminum species and monometallic platinum complexes in which the ligand chelates to the metal through the two phosphorus donor atoms.

  DOI：

  10.1021/om060014z

文献信息

• Coordination Chemistry of Isomeric Mixtures of Linked Di(phosphaguanidine) Compounds:  A Spectroscopic and Crystallographic Study
  作者：Natalie E. Mansfield、Martyn P. Coles、Anthony G. Avent、Peter B. Hitchcock

  DOI：10.1021/om060014z

  日期：2006.5.1

  Multinuclear NMR spectroscopy and X-ray diffraction techniques have been used to identify diastereomeric mixtures of rac- and meso-di(phosphaguanidine) compounds. A brief survey of their coordination chemistry has demonstrated the formation of N,N'-bound bimetallic aluminum species and monometallic platinum complexes in which the ligand chelates to the metal through the two phosphorus donor atoms.