3-Trifluormethylphthalonitril | 64219-34-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-Trifluormethylphthalonitril
• 英文别名: 3-(Trifluoromethyl)phthalonitrile；3-(trifluoromethyl)benzene-1,2-dicarbonitrile
• CAS: 64219-34-7
• 化学式: C₉H₃F₃N₂
• 分子量: 196.131
• InChiKey: MBFWTYDIPGKKBX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  3-Trifluormethylphthalimid 在 吡啶 、 氨 、 三氯氧磷 作用下， 生成 3-Trifluormethylphthalonitril
  参考文献：
  名称：

  Oksengendler,I.G. et al., Journal of Organic Chemistry USSR (English Translation), 1977, vol. 13, p. 1430 - 1434

  摘要：

  DOI：

文献信息

• Method for producing of phthalocyanine compound
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0882768A2

  公开（公告）日：1998-12-09

  A method for producing a novel phthalocyanine compound which excels in yield and purity, allows no introduction of a chlorine atom into the phthalocyanine skeleton, and possesses relatively bulky substituents is provided. This method is characterized by causing an orthophthalonitrile compound having a substituent exhibiting smaller σp values than σm values in the Hammett's rule to react with a metal oxide in the presence of a compound forming in the aqueous solution thereof at 25°C an acid or conjugate acid having a dissociation index pKa (the logarithmic value of the reciprocal of the dissociation constant of the acid or conjugate acid) of not more than 7.0.

  本发明提供了一种生产新型酞菁化合物的方法，该方法产量高、纯度高，不允许在酞菁骨架中引入氯原子，并具有相对笨重的取代基。 该方法的特点是，在 25°C 时，在其水溶液中形成的酸或共轭酸的化合物存在下，使具有取代基的 σp 值小于哈密特规则中的σm 值的邻苯二甲腈化合物与金属氧化物反应，该酸或共轭酸的离解指数 pKa（酸或共轭酸的离解常数倒数的对数值）不大于 7.0。
• AN ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING A SUBSTRATE, AN ANODE LAYER AND A CATHODE LAYER, AT LEAST ONE LIGHT EMITTING LAYER, AND AT LEAST ONE SEMICONDUCTOR LAYER THAT COMPRISES AT LEAST ONE METAL COMPOUND OF A METAL AND AT LEAST ONE LIGAND
  申请人：Novaled GmbH

  公开号：EP4105201A1

  公开（公告）日：2022-12-21

  The present invention relates to an organic electroluminescent device comprising a substrate, an anode layer and a cathode layer, at least one light emitting layer, and at least one semiconductor layer or more, wherein the at least one semiconductor layer comprises at least one metal compound, wherein the metal compound comprises a metal M and at least one ligand L.

  本发明涉及一种有机电致发光器件，包括基板、阳极层和阴极层、至少一个发光层和至少一个或多个半导体层，其中至少一个半导体层包括至少一种金属化合物，金属化合物包括金属 M 和至少一种配体 L。
• Photoelectric conversion film, solid state imaging element, and electronic device
  申请人：SONY SEMICONDUCTOR SOLUTIONS CORPORATION

  公开号：US10367153B2

  公开（公告）日：2019-07-30

  Provided is a photoelectric conversion film containing a subphthalocyanine derivative represented by general formula (1) below, in which, in the general formula (1),at least one or more of X1 and X2, at least one or more of X3 and X4, and at least one or more of X5 and X6 are a partial fluoroalkyl group substituted with two or more fluorine atoms or a perfluoroalkyl group, and Z is any substituent capable of binding to boron.

  本发明提供了一种光电转换薄膜，其中含有如下通式 (1) 所代表的亚酞菁衍生物、 其中，在通式（1）中，X1 和 X2 中的至少一个或多个、X3 和 X4 中的至少一个或多个、X5 和 X6 中的至少一个或多个是被两个或多个氟原子取代的偏氟烷基或全氟化烷基，Z 是能与硼结合的任何取代基。
• PHOTOELECTRIC CONVERSION FILM, SOLID STATE IMAGING ELEMENT, AND ELECTRONIC DEVICE
  申请人：SONY SEMICONDUCTOR SOLUTIONS CORPORATION

  公开号：US20180342683A1

  公开（公告）日：2018-11-29

  [Object] To improve imaging characteristics of a solid state imaging element. [Solution] Provided is a photoelectric conversion film containing a subphthalocyanine derivative represented by general formula (1) below, in which, in the general formula (1), at least one or more of X 1 and X 2 , at least one or more of X 3 and X 4 , and at least one or more of X 5 and X 6 are a partial fluoroalkyl group substituted with two or more fluorine atoms or a perfluoroalkyl group, and Z is any substituent capable of binding to boron.
• US6034236A
  申请人：——

  公开号：US6034236A

  公开（公告）日：2000-03-07