4-(bis(4-methoxyphenyl)amino)benzaldehyde N-4-vinylbenzyl-N-phenylhydrazone | 1379595-63-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-(bis(4-methoxyphenyl)amino)benzaldehyde N-4-vinylbenzyl-N-phenylhydrazone
• CAS: 1379595-63-7
• 化学式: C₃₆H₃₃N₃O₂
• 分子量: 539.677
• InChiKey: PRBVKNBRLMZJRW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.86
• 重原子数：
  41.0
• 可旋转键数：
  11.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  37.3
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  4-二对甲氧基苯胺基苯甲醛 在 四丁基硫酸氢铵 、 potassium hydroxide 作用下， 以 甲醇 、 丙酮 为溶剂， 反应 1.0h， 生成 4-(bis(4-methoxyphenyl)amino)benzaldehyde N-4-vinylbenzyl-N-phenylhydrazone
  参考文献：
  名称：

  Synthesis and properties of triphenylamine-based hydrazones with reactive vinyl groups

  摘要：

  Two triphenylamine-based hydrazones with reactive vinyl groups were synthesized and characterized. The optical, thermal, electrochemical and photoelectrical properties of the obtained compounds were studied. All the synthesized hydrazone monomers form glasses with the glass transition temperatures ranging from 52 degrees C to 82 degrees C. The electron photoemission spectra of the synthesized hydrazones were recorded and ionization potentials of 5.22-5.29 eV were established. Room temperature hole-drift mobilities in the amorphous film of hydrazone monomer having three vinyl groups established by xerographic time-of-flight technique was found to be 3.5 x 10(-3) cm(2)/V.s at an electric field of 6.4 x 10(5) cm(2)/V.s. Self-polymerization of the hydrazones bearing vinyl groups was demonstrated by differential scanning calorimetry. Self-polymerization of monomers containing one and three vinyl groups started at 151 degrees C and 136 degrees C, while maximum polymerization rates were observed at 209 degrees C and 167 degrees C respectively. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2012.03.010