2,2-bis[4-{(3-ethyl-oxetane-3-yl)methoxy}phenyl]propane | 105071-04-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-bis[4-{(3-ethyl-oxetane-3-yl)methoxy}phenyl]propane
• 英文别名: 2,2-bis[4-{(3-ethyloxetan-3-yl)methoxy}phenyl]propane；3-Ethyl-3-[[4-[2-[4-[(3-ethyloxetan-3-yl)methoxy]phenyl]propan-2-yl]phenoxy]methyl]oxetane
• CAS: 105071-04-3
• 化学式: C₂₇H₃₆O₄
• 分子量: 424.58
• InChiKey: LKHRYYYKDKAOOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  31
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• NOVEL AROMATIC SULFONIUM COMPOUNDS, PHOTOACID GENERATORS COMPRISING THE SAME, PHOTOPOLYMERIZABLE COMPOSITIONS CONTAINING THE SAME, STEREOLITHOGRAPHIC RESIN COMPOSITIONS, AND STEREOLITHOGRAPHIC PROCESS
  申请人：ASAHI DENKA KOGYO KABUSHIKI KAISHA

  公开号：EP1036789A1

  公开（公告）日：2000-09-20

  Novel aromatic sulfonium compounds of general formula (I), photoacid generators comprising the same, and photopolymerizable compositions containing the same, capable of providing stereolithographic resin compositions which do not suffer from the hindrance to curing by oxygen, can easily give shaped articles having desired sizes by virtue of the high accuracy thereof in curing, and can attain a satisfactory curing depth owing to the high sensitivity thereof for radiant energy; and a stereolithographic process.

  通式(I)的新型芳香族锍化合物、包含这种化合物的光酸发生器和包含这种化合物的可光聚合组合物，能够提供不受氧气固化阻碍的立体平版印刷树脂组合物，由于其固化精度高，可以很容易地得到具有所需尺寸的成型物品，并且由于其对辐射能的高灵敏度，可以达到令人满意的固化深度；以及一种立体平版印刷工艺。
• Novel aromatic sulfonium salt compound, photo-acid generator comprising the same and photopolymerizable composition containing the same, resin composition for optical three-dimensional shaping, and method of optically forming three-dimensional shape
  申请人：Adeka Corporation

  公开号：EP2308865A1

  公开（公告）日：2011-04-13

  Novel aromatic sulfonium salt compounds of general formula (I), photo-acid generators comprising the same, and photo-polymerizable compositions containing the same, capable of providing stereolithographic resin compositions which do not suffer from the hindrance to curing by oxygen, can easily give shaped articles having desired sizes by virtue of the high accuracy thereof in curing, can attain a satisfactory curing depth owing to the high sensitivity thereof for radiant energy and can be employed for wide usage, such as photoresist and ink for foods-packing medium, since the release of benzene is suppressed; and a stereolithographic process, using said stereolithographic resin composition.

  通式(I)的新型芳香族锍盐化合物、包含这些化合物的光酸发生器以及包含这些化合物的可光聚合组合物，能够提供不受氧气固化阻碍的立体平版印刷树脂组合物、由于其固化精度高，可以很容易地生产出具有所需尺寸的成型物品；由于其对辐射能的敏感度高，可以达到令人满意的固化深度；由于抑制了苯的释放，可以广泛用于食品包装介质的光刻胶和油墨等；使用所述立体平版印刷树脂组合物的立体平版印刷工艺。
• SULFONIC ACID DERIVATIVE COMPOUND, PHOTOACID GENERATOR, RESIST COMPOSITION, CATIONIC POLYMERIZATION INITIATOR, AND CATIONICALLY POLYMERIZABLE COMPOSITION
  申请人：Adeka Corporation

  公开号：EP3272737A1

  公开（公告）日：2018-01-24

  Provide are: a sulfonic acid derivative compound which has high absorbance for light having a wavelength of 365 nm and exhibits high solubility in organic solvents and good acid generation rate; a photoacid generator; a resist composition; a cationic polymerization initiator; and a cationically polymerizable composition. The sulfonic acid derivative compound is represented by the following Formula (I): (wherein, X represents a linear or branched alkyl group having 1 to 14 carbon atoms; and R represents an aliphatic hydrocarbon group having 1 to 18 carbon atoms, an aryl group having 6 to 20 carbon atoms, an arylalkyl group having 7 to 20 carbon atoms, an acyl group-substituted aryl group having 7 to 20 carbon atoms, an alicyclic hydrocarbon group having 3 to 12 carbon atoms, a 10-camphoryl group or the like).

  提供：一种磺酸衍生物化合物，它对波长为 365 纳米的光具有高吸收率，在有机溶剂中具有高溶解性和良好的酸生成率；一种光酸发生器；一种抗蚀剂组合物；一种阳离子聚合引发剂；以及一种阳离子可聚合组合物。磺酸衍生物化合物由下式（I）表示： (其中，X 代表具有 1 至 14 个碳原子的直链或支链烷基；R 代表具有 1 至 18 个碳原子的脂肪族烃基、具有 6 至 20 个碳原子的芳基、具有 7 至 20 个碳原子的芳烷基、具有 7 至 20 个碳原子的酰基取代的芳基、具有 3 至 12 个碳原子的脂环族烃基、10-樟脑基或类似基团）。
• AROMATIC SULFONIUM SALT COMPOUND, PHOTOACID GENERATOR, RESIST COMPOSITION, CATIONIC POLYMERIZATION INITIATOR, AND CATIONICALLY POLYMERIZABLE COMPOSITION
  申请人：Adeka Corporation

  公开号：EP3272744A1

  公开（公告）日：2018-01-24

  Provided are: an aromatic sulfonium salt compound which exhibits low corrosion to a substrate and excellent photolithographic characteristics and is thus useful as a photoacid generator and as a cationic polymerization agent; and a photoacid generator, a resist composition, a cationic polymerization initiator and a cationically polymerizable agent composition, which include the aromatic sulfonium salt compound. The aromatic sulfonium salt compound is represented by the following Formula (I): (wherein, R1 to R10 each independently represent a hydrogen atom, a halogen atom, a hydroxyl group, a nitro group, a cyano group, an alkyl group having 1 to 18 carbon atoms which is optionally substituted, or the like; R11 to R15 each independently represent a hydrogen atom, an alkoxy group having 1 to 18 carbon atoms which is optionally substituted, or the like; at least one of R11 to R15 is not a hydrogen atom; and X1- represents a monovalent organic sulfonate anion).

  本发明提供了：一种芳香族锍盐化合物，该化合物对基底的腐蚀性低，具有优异的光刻特性，因此可用作光酸发生剂和阳离子聚合剂；以及一种光酸发生剂、一种抗蚀剂组合物、一种阳离子聚合引发剂和一种阳离子可聚合剂组合物，其中包括该芳香族锍盐化合物。芳香族锍盐化合物由下式（I）表示： (其中，R1 至 R10 各自独立地代表氢原子、卤素原子、羟基、硝基、氰基、具有 1 至 18 个碳原子且被任选取代的烷基或类似基团；R11 至 R15 各自独立地代表氢原子、具有 1 至 18 个碳原子且被任选取代的烷氧基或类似基团；R11 至 R15 中至少有一个不是氢原子；以及 X1- 代表一价有机磺酸盐阴离子）。
• MOLDED BODY COMPRISING ACRYLIC RESIN COMPOSITION
  申请人：Kuraray Co., Ltd.

  公开号：EP3476595A1

  公开（公告）日：2019-05-01

  A multi-layer shaped product, comprising a layer composed of an acrylic resin composition comprising a (meth)acrylic resin (A) and an acrylic block copolymer (B) comprising an acrylic acid ester polymer block (a) and a methacrylic acid ester polymer block (b), and if necessary, particles of an acrylic elastomeric polymer (C), and a layer composed of an active energy ray cured resin that is in contact with the layer composed of the acrylic resin composition, wherein an amount of the acrylic block copolymer (B) comprised in the acrylic resin composition is not less than 1 part by mass and not more than 60 parts by mass based on 100 parts by mass of the acrylic resin composition.

  一种多层成型产品，包括由丙烯酸树脂组合物组成的一层，该树脂组合物由（甲基）丙烯酸树脂（A）和丙烯酸嵌段共聚物（B）组成，该丙烯酸嵌段共聚物由丙烯酸酯聚合物嵌段（a）和甲基丙烯酸酯聚合物嵌段（b）组成，必要时还包括丙烯酸弹性聚合物颗粒（C）、和由活性能量射线固化树脂组成的层，该层与由丙烯酸树脂组合物组成的层接触，其中丙烯酸树脂组合物中的丙烯酸嵌段共聚物（B）的含量以 100 份丙烯酸树脂组合物的质量为基准，不小于 1 份，不大于 60 份。