4-((E)-2-(4-bromonaphthalen-1-yl)vinyl)-N-(4-((E)-2-(4-bromonaphthalen-1-yl)vinyl)phenyl)-N-(4-((E)-2-(4-((E)-2-(pyridin-4-yl)vinyl)naphthalen-1-yl)vinyl)phenyl)benzenamide | 1246751-63-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-((E)-2-(4-bromonaphthalen-1-yl)vinyl)-N-(4-((E)-2-(4-bromonaphthalen-1-yl)vinyl)phenyl)-N-(4-((E)-2-(4-((E)-2-(pyridin-4-yl)vinyl)naphthalen-1-yl)vinyl)phenyl)benzenamide
• 英文别名: N,N-bis[4-[(E)-2-(4-bromonaphthalen-1-yl)ethenyl]phenyl]-4-[(E)-2-[4-[(E)-2-pyridin-4-ylethenyl]naphthalen-1-yl]ethenyl]aniline
• CAS: 1246751-63-2
• 化学式: C₆₁H₄₂Br₂N₂
• 分子量: 962.826
• InChiKey: CGEBCPJJSVALTL-HWWGJKEPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18.3
• 重原子数：
  65
• 可旋转键数：
  11
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  16.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-乙烯基吡啶 、 tris(4-(2-(4-bromonaphthalen-1-yl)vinyl)phenyl)amine 在 palladium diacetate 、 三乙胺 、 三(邻甲基苯基)磷 作用下， 以 乙腈 为溶剂， 反应 24.0h， 以0.125 g的产率得到4-((E)-2-(4-bromonaphthalen-1-yl)vinyl)-N-(4-((E)-2-(4-bromonaphthalen-1-yl)vinyl)phenyl)-N-(4-((E)-2-(4-((E)-2-(pyridin-4-yl)vinyl)naphthalen-1-yl)vinyl)phenyl)benzenamide
  参考文献：
  名称：

  Novel D–π3–(A)1–3 multibranched chromophores as an efficient two-photon-induced polymerization initiator

  摘要：

  The ability of novel branched chromophores that contained a triphenylamine group as donor, naphthalene as pi-bridge and pyridyl as acceptor group, to act as two-photon absorption and two-photon induced polymerization initiators were investigated Linear and nonlinear optical spectra revealed that chromophores with large dipolar moment change gave strong intramolecular charge-transfer characteristics that exhibited enhanced two-photon absorption cross-section A variety of micro-objects were fabricated, using an acrylate matrix, that contained the novel chromophores as two-photon induced polymerization initiator Molecular energy levels, electrochemistry and linear absorption spectra, as well as one-photon fluorescence quenching measurements supported the hypothesis that two-photon induced polymerization proceeds via intermolecular charge-transfer from initiator to monomer and, that the chromophore firstly generates the exciton via two-photon absorption and then transfers charge to the acrylate monomer which then polymerises (C) 2010 Elsevier Ltd. All rights reserved

  DOI：

  10.1016/j.dyepig.2010.05.001

文献信息

• Novel D–π3–(A)1–3 multibranched chromophores as an efficient two-photon-induced polymerization initiator
  作者：Xiaomei Wang、Feng Jin、Weizhou Zhang、Xutang Tao、Xuan-Ming Duan、Minhua Jiang

  DOI：10.1016/j.dyepig.2010.05.001

  日期：2011.1

  The ability of novel branched chromophores that contained a triphenylamine group as donor, naphthalene as pi-bridge and pyridyl as acceptor group, to act as two-photon absorption and two-photon induced polymerization initiators were investigated Linear and nonlinear optical spectra revealed that chromophores with large dipolar moment change gave strong intramolecular charge-transfer characteristics that exhibited enhanced two-photon absorption cross-section A variety of micro-objects were fabricated, using an acrylate matrix, that contained the novel chromophores as two-photon induced polymerization initiator Molecular energy levels, electrochemistry and linear absorption spectra, as well as one-photon fluorescence quenching measurements supported the hypothesis that two-photon induced polymerization proceeds via intermolecular charge-transfer from initiator to monomer and, that the chromophore firstly generates the exciton via two-photon absorption and then transfers charge to the acrylate monomer which then polymerises (C) 2010 Elsevier Ltd. All rights reserved