2'-Phenylspiro[bicyclo[4.1.0]heptane-7,4'-cyclopent-2-ene]-1'-one | 1432909-50-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2'-Phenylspiro[bicyclo[4.1.0]heptane-7,4'-cyclopent-2-ene]-1'-one
• 英文别名: 2'-phenylspiro[bicyclo[4.1.0]heptane-7,4'-cyclopent-2-ene]-1'-one
• CAS: 1432909-50-6；185808-87-1
• 化学式: C₁₇H₁₈O
• 分子量: 238.329
• InChiKey: STTJBUXVTCNBBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  (phenylacetylene)hexacarbonyldicobalt 、 7-methylenebicyclo[4.1.0]heptane 以 甲苯 为溶剂， 反应 0.08h， 生成 4'-phenylspiro[bicyclo[4.1.0]heptane-7,1'-cyclopentan]-3'-en-2'-one 、 2'-Phenylspiro[bicyclo[4.1.0]heptane-7,4'-cyclopent-2-ene]-1'-one 、
  参考文献：
  名称：

  Pauson–Khand Reactions in a Photochemical Flow Microreactor

  摘要：

  Pauson-Khand reactions were achieved at ambient temperature without any additive using a photochemical flow microreactor. The efficiency of the reaction was better than that in a conventional batch reactor, and the reaction could be operated continuously for 1 h.

  DOI：

  10.1021/ol4008519

文献信息

• Pauson–Khand Reactions in a Photochemical Flow Microreactor
  作者：Keisuke Asano、Yuki Uesugi、Jun-ichi Yoshida

  DOI：10.1021/ol4008519

  日期：2013.5.17

  Pauson-Khand reactions were achieved at ambient temperature without any additive using a photochemical flow microreactor. The efficiency of the reaction was better than that in a conventional batch reactor, and the reaction could be operated continuously for 1 h.