(4-Methoxyphenyl)methyl cyclobutene-1-carboxylate | 1313022-84-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4-Methoxyphenyl)methyl cyclobutene-1-carboxylate
• 英文别名: (4-methoxyphenyl)methyl cyclobutene-1-carboxylate
• CAS: 1313022-84-2
• 化学式: C₁₃H₁₄O₃
• 分子量: 218.252
• InChiKey: QPLMXWGVSXMMGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1-环丁烯-1-羧酸 、 4-甲氧基苄醇 在 4-二甲氨基吡啶 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 以13.7%的产率得到(4-Methoxyphenyl)methyl cyclobutene-1-carboxylate
  参考文献：
  名称：

  Accelerated Ring-Opening Metathesis Polymerization of a Secondary Amide of 1-Cyclobutene by Hydrogen-Bonding Interaction

  摘要：

  A hydrogen-bond-assisted model is proposed for ring-opening metathesis polymerization (ROMP) of a secondary amide of 1-cyclobutene, resulting in the fastest reaction rate in a nonpolar solvent, toluene. This new model was supported by the investigation on how the solvent effect affected the NMR spectra, ROMP kinetic studies, and the copolymerization of monomers 1 and 2.

  DOI：

  10.1021/ol2014363

文献信息

• Accelerated Ring-Opening Metathesis Polymerization of a Secondary Amide of 1-Cyclobutene by Hydrogen-Bonding Interaction
  作者：Kil Sun Lee、Tae-Lim Choi

  DOI：10.1021/ol2014363

  日期：2011.8.5

  A hydrogen-bond-assisted model is proposed for ring-opening metathesis polymerization (ROMP) of a secondary amide of 1-cyclobutene, resulting in the fastest reaction rate in a nonpolar solvent, toluene. This new model was supported by the investigation on how the solvent effect affected the NMR spectra, ROMP kinetic studies, and the copolymerization of monomers 1 and 2.