trans-tetrabromobis(pyridine)silicon | 18861-94-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: trans-tetrabromobis(pyridine)silicon
• 英文别名: pyridine; compound with tetrabromosilane；Pyridin; Verbindung mit Tetrabromsilan
• CAS: 18861-94-4
• 化学式: Br₄Si*2C₅H₅N
• 分子量: 505.904
• InChiKey: OFSRHPJZOKSYLQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  吡啶 在 溴化硅(IV) 作用下， 以 氯仿 为溶剂， 反应 3.0h， 生成 trans-tetrabromobis(pyridine)silicon
  参考文献：
  名称：

  摘要：

  The crystal structures of trans-tetrabromobis(pyridine)silicon (1) and trans-tetrabromobis(3,5-dimethylpyridine)silicon (2) have been determined: (1) crystallizes in the monoclinic space group C2/m with cell dimensions a = 14.4250(2) Angstrom, b = 7.3055(1) Angstrom, c = 7.2539(1) Angstrom, beta = 117.660(1)degrees, (2) crystallizes in the monoclinic space group C2/m with cell dimensions a = 16.013(3) Angstrom, b = 7.316(1) Angstrom, c = 8.179(2) Angstrom; beta = 113.19(1)degrees. Both molecules, with D-2h symmetry, have crystallographic C-2h site symmetry. The environment about the Si atoms can be described as a slightly distorted octahedron with the pyridyl ligands occupying axial positions and the four bromo ligands in the equatorial plane.

  DOI：

  10.1023/a:1009591022507