6-N-pyridin-2-yl-2-N-pyridin-3-ylpyridine-2,6-dicarboxamide | 1394293-08-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 6-N-pyridin-2-yl-2-N-pyridin-3-ylpyridine-2,6-dicarboxamide
• CAS: 1394293-08-3
• 化学式: C₁₇H₁₃N₅O₂
• 分子量: 319.323
• InChiKey: QZYOAMFSNHSFAM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  96.9
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  四乙基氯化铵一水合物 、 cobalt(II) diacetate tetrahydrate 、 6-N-pyridin-2-yl-2-N-pyridin-3-ylpyridine-2,6-dicarboxamide 在 K₂CO₃ 作用下， 以 二氯甲烷 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  A novel Co3+-based asymmetrical building block: Heterobimetallic metallacycles versus coordination networks

  摘要：

  A new Co3+-based asymmetrical building block (1) offering both 2-pyridyl and 3-pyridyl appended groups has been synthesized and utilized for preparing heterobimetallic systems. The reactions of 1 with secondary metals afforded {Co3+-2n(2+)} metallacycle (2). {Co3+-Cd2+} metallacycle-based coordination polymer (3) and a {Co3+-Hg2+} coordination chain (4). The crystallographic studies reveal the importance of asymmetrical building block in generating unique structural motifs. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2012.06.018

文献信息

• A novel Co3+-based asymmetrical building block: Heterobimetallic metallacycles versus coordination networks
  作者：Girijesh Kumar、Rajeev Gupta

  DOI：10.1016/j.inoche.2012.06.018

  日期：2012.9

  A new Co3+-based asymmetrical building block (1) offering both 2-pyridyl and 3-pyridyl appended groups has been synthesized and utilized for preparing heterobimetallic systems. The reactions of 1 with secondary metals afforded Co3+-2n(2+)} metallacycle (2). Co3+-Cd2+} metallacycle-based coordination polymer (3) and a Co3+-Hg2+} coordination chain (4). The crystallographic studies reveal the importance of asymmetrical building block in generating unique structural motifs. (C) 2012 Elsevier B.V. All rights reserved.