4,4,5,5,6,6-Hexafluoro-1-(4,4,5,5,6,6-hexafluorocyclopenta[c]thiophen-3-yl)-3-[4,4,5,5,6,6-hexafluoro-3-[4,4,5,5,6,6-hexafluoro-1-[4,4,5,5,6,6-hexafluoro-1-(4,4,5,5,6,6-hexafluorocyclopenta[c]thiophen-3-yl)cyclopenta[c]thiophen-3-yl]cyclopenta[c]thiophen-3-yl]cyclopenta[c]thiophen-1-yl]cyclopenta[c]thiophene | 928846-20-2

分子结构分类

有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩

中文名称

——

中文别名

——

英文名称

4,4,5,5,6,6-Hexafluoro-1-(4,4,5,5,6,6-hexafluorocyclopenta[c]thiophen-3-yl)-3-[4,4,5,5,6,6-hexafluoro-3-[4,4,5,5,6,6-hexafluoro-1-[4,4,5,5,6,6-hexafluoro-1-(4,4,5,5,6,6-hexafluorocyclopenta[c]thiophen-3-yl)cyclopenta[c]thiophen-3-yl]cyclopenta[c]thiophen-3-yl]cyclopenta[c]thiophen-1-yl]cyclopenta[c]thiophene

英文别名

4,4,5,5,6,6-hexafluoro-1-(4,4,5,5,6,6-hexafluorocyclopenta[c]thiophen-3-yl)-3-[4,4,5,5,6,6-hexafluoro-3-[4,4,5,5,6,6-hexafluoro-1-[4,4,5,5,6,6-hexafluoro-1-(4,4,5,5,6,6-hexafluorocyclopenta[c]thiophen-3-yl)cyclopenta[c]thiophen-3-yl]cyclopenta[c]thiophen-3-yl]cyclopenta[c]thiophen-1-yl]cyclopenta[c]thiophene

CAS

928846-20-2

化学式

C₄₂H₂F₃₆S₆

mdl

——

分子量

1382.82

InChiKey

QFEMLDRFTRMKEV-UHFFFAOYSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

16.5
重原子数：

84
可旋转键数：

5
环数：

12.0
sp3杂化的碳原子比例：

0.43
拓扑面积：

169
氢给体数：

0
氢受体数：

42

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	4,4,5,5,6,6-Hexafluoro-3-(4,4,5,5,6,6-hexafluorocyclopenta[c]thiophen-3-yl)cyclopenta[c]thiophene	928846-21-3	C₁₄H₂F₁₂S₂	462.283

反应信息

作为产物：

描述：

4,4,5,5,6,6-Hexafluoro-3-(4,4,5,5,6,6-hexafluorocyclopenta[c]thiophen-3-yl)cyclopenta[c]thiophene 在正丁基锂、 iron(III) acetylacetonate 作用下，以乙醚、四氢呋喃为溶剂，反应 1.5h，以45%的产率得到4,4,5,5,6,6-Hexafluoro-1-(4,4,5,5,6,6-hexafluorocyclopenta[c]thiophen-3-yl)-3-[4,4,5,5,6,6-hexafluoro-1-(4,4,5,5,6,6-hexafluorocyclopenta[c]thiophen-3-yl)cyclopenta[c]thiophen-3-yl]cyclopenta[c]thiophene

参考文献：

名称：

Electronegative Oligothiophenes Fully Annelated with Hexafluorocyclopentene: Synthesis, Properties, and Intrinsic Electron Mobility

摘要：

Synthesis of hexafluorocyclopenta[c]thiophene-repeated oligothiophenes up to 6-mer has been accomplished. The photophysical and electrochemical properties of these oligomers unambiguously exemplify marked electronegative character without disrupting the effective conjugation. The combination of time-resolved microwave conductivity and transient optical spectroscopy measurements of the 6-mer revealed the intrinsic electron mobility to be as high as 2.0 x 10(-1) cm(2) V-1 S-1.

DOI：

10.1021/ol703016g

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同类化合物

锡烷,1,1'-(3,3'-二烷基[2,2'-二噻吩]-5,5'-二基)双[1,1,1-三甲基- 试剂5,10-Bis((5-octylthiophen-2-yl)dithieno[2,3-d:2',3'-d']benzo[1,2-b:4,5-b']dithiophene-2,7-diyl)bis(trimethylstannane) 试剂2,2'-Thieno[3,2-b]thiophene-2,5-diylbis-3-thiophenecarboxylicacid 试剂1,1'-[4,8-Bis[5-(dodecylthio)-2-thienyl]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl]bis[1,1,1-trimethylstannane] 苯并[b]噻吩,3-(2-噻嗯基)- 聚（3-己基噻吩-2,5-二基）（区域规则）甲基[2,3'-联噻吩]-5-羧酸甲酯牛蒡子醇 B 噻吩并[3,4-B]吡嗪,5,7-二-2-噻吩- 噻吩[3,4-B]吡嗪,5,7-双(5-溴-2-噻吩)- 十四氟-Alpha-六噻吩三丁基(5''-己基-[2,2':5',2''-三联噻吩]-5-基)锡 α-四联噻吩 α-六噻吩 α-五联噻吩 α-七噻吩 α,ω-二己基四噻吩 5,5′-双(3-己基-2-噻吩基)-2,2′-联噻吩 α,ω-二己基六联噻吩 Α-八噻吩 alpha-三联噻吩甲醇 alpha-三联噻吩 [3,3-Bi噻吩]-2,2-二羧醛 [2,2’]-双噻吩-5,5‘-二甲醛 [2,2':5',2''-三联噻吩]-5,5''-二基双[三甲基硅烷] [2,2'-联噻吩]-5-甲醇,5'-(1-丙炔-1-基)- [2,2'-联噻吩]-5-甲酸甲酯 [2,2'-联噻吩]-5-乙酸,a-羟基-5'-(1-炔丙基)-(9CI) IN1538,4,6-双(4-癸基噻吩基)-噻吩并[3,4-C][1,2,5]噻二唑(S) C-[2,2-二硫代苯-5-基甲基]胺 6,6,12,12-四(4-己基苯基)-6,12-二氢二噻吩并[2,3-D:2',3'-D']-S-苯并二茚并[1,2-B:5,6-B']二噻吩-2,8-双三甲基锡 5’-己基-2,2’-联噻吩-5-硼酸频哪醇酯 5-辛基-1,3-二（噻吩-2-基）-4H-噻吩并[3,4-c]吡咯-4,6（5H）-二酮 5-苯基-2,2'-联噻吩 5-溴5'-辛基-2,2'-联噻吩 5-溴-5′-己基-2,2′-联噻吩 5-溴-5'-甲酰基-2,2':5'2'-三噻吩 5-溴-3,3'-二己基-2,2'-联噻吩 5-溴-3'-癸基-2,2':5',2''-三联噻吩 5-溴-2,2-双噻吩 5-溴-2,2'-联噻吩-5'-甲醛 5-氯-5'-苯基-2,2'-联噻吩 5-氯-2,2'-联噻吩 5-正辛基-2,2'-并噻吩 5-己基-5'-乙烯基-2,2'-联噻吩 5-己基-2,2-二噻吩 5-全氟己基-5'-溴-2,2'-二噻吩 5-全氟己基-2,2′-联噻吩 5-乙酰基-2,2-噻吩基 5-乙氧基-2,2'-联噻吩 5-丙酰基-2,2-二噻吩

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