| 250750-42-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 250750-42-6
• 化学式: C₁₈H₂₈OSi
• 分子量: 288.505
• InChiKey: FIZVEVRVKDMTCV-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 四丁基氟化铵 作用下， 生成 4-(2-Propan-2-ylidenecyclopropyl)phenol
  参考文献：
  名称：

  Facile Autoxidation of 2-(4-Hydroxy- phenyl)-3,3-dimethylmethylenecyclopropane. The Radical Stabilizing Ability of the Phenoxide Group

  摘要：

  2-(4-Hydroxyphenyl)-3,3-dimethylmethylenecyclopropane undergoes rapid reaction with O-2 at room temperature to give a dioxolane, A chain mechanism involving ring opening of a phenoxy radical is proposed. Conversion of the title compound to the phenoxide results in a remarkably accelerated methylenecyclopropane rearrangement. Computational studies suggest that the intermediate biradical is greatly stabilized by the phenoxide substituent.

  DOI：

  10.1021/ol9902576
• 作为产物：
  描述：

  Tert-butyl-[4-(2,2-dimethyl-3-methylidenecyclopropyl)phenoxy]-dimethylsilane 生成
  参考文献：
  名称：

  Facile Autoxidation of 2-(4-Hydroxy- phenyl)-3,3-dimethylmethylenecyclopropane. The Radical Stabilizing Ability of the Phenoxide Group

  摘要：

  2-(4-Hydroxyphenyl)-3,3-dimethylmethylenecyclopropane undergoes rapid reaction with O-2 at room temperature to give a dioxolane, A chain mechanism involving ring opening of a phenoxy radical is proposed. Conversion of the title compound to the phenoxide results in a remarkably accelerated methylenecyclopropane rearrangement. Computational studies suggest that the intermediate biradical is greatly stabilized by the phenoxide substituent.

  DOI：

  10.1021/ol9902576