phenyl butylphosphinate | 21655-99-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenyl butylphosphinate
• CAS: 21655-99-2
• 化学式: C₁₀H₁₅O₂P
• 分子量: 198.202
• InChiKey: DYPYKMYYQOJQRF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.34
• 重原子数：
  13.0
• 可旋转键数：
  5.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  26.3
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  n-butylphosphinic acid 、 苯酚 生成 phenyl butylphosphinate
  参考文献：
  名称：

  Nifant'ev,E.E. et al., Journal of applied chemistry of the USSR, 1969, vol. 42, p. 2443 - 2446

  摘要：

  DOI：

文献信息

• Selective Hydrogenation Catalyst and Methods of Making and Using Same
  申请人：Cheung Tin-Tack Peter

  公开号：US20100228065A1

  公开（公告）日：2010-09-09

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.

  一种包括支持的氢化催化剂的组合物，其中氢化催化剂包括钯和有机磷化合物，支持的氢化催化剂能够选择性地将高度不饱和烃氢化为不饱和烃。一种制备选择性氢化催化剂的方法，包括将支持物与含钯化合物接触以形成支持的钯组合物，将支持的钯组合物与有机磷化合物接触以形成催化剂前体，并还原催化剂前体以形成催化剂。一种将高度不饱和烃选择性氢化为富含不饱和烃的组合物的方法，包括将包括钯和有机磷化合物的支持催化剂与含高度不饱和烃的进料接触，在适宜的氢化条件下至少部分氢化高度不饱和烃进料以形成富含不饱和烃的组合物。
• Catalyst composition for a polyester manufacturing process
  申请人：Clariant International Ltd.

  公开号：EP3000835A1

  公开（公告）日：2016-03-30

  The present invention relates to catalyst composition for a polyester manufacturing process, comprising a titanium catalyst and/or an antimony catalyst as main catalyst, and either (i) at least one co-catalyst A, or (ii) at least one co-catalyst B and at least one co-catalyst C, or (iii) a combination thereof, and wherein co-catalyst A is selected from the group consisting of a metal salt of an alkyl or an aryl phosphinic acid, or a metal salt of an alkyl or aryl diphosphinic acid, or a combination thereof, and co-catalyst B is selected from the group consisting of an alkyl or aryl phosphinic acid, an alkyl or aryl diphosphinic acid a combination thereof, and co-catalyst C selected from the group of a metal salt, a metal hydroxide or a metal organyl compound.

  本发明涉及用于聚酯生产工艺的催化剂组合物，该组合物包括作为主催化剂的钛 催化剂和/或锑催化剂，以及 (i) 至少一种助催化剂 A，或 (ii) 至少一种助催化剂 B 和至少一种助催化剂 C，或 (iii) 它们的组合，以及 其中助催化剂 A 选自烷基或芳基膦酸的金属盐或烷基或芳基二膦酸的金属盐或其组合组成的组，助催化剂 B 选自烷基或芳基膦酸或烷基或芳基二膦酸或其组合组成的组，助催化剂 C 选自金属盐、金属氢氧化物或金属羰基化合物组成的组。
• SELECTIVE HYDROGENATION CATALYST AND METHODS OF MAKING AND USING SAME
  申请人：Chevron Phillips Chemical Company LP

  公开号：EP3144064A2

  公开（公告）日：2017-03-22

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons.

  一种由钯和有机磷化合物组成的载体加氢催化剂组成的组合物，该载体加氢催化剂能选择性地将高度不饱和烃加氢为不饱和烃。
• NON-HALOGEN FLAME-RETARDANT RESIN COMPOSITION AND FLAME-RETARDANT RESIN MOLDED ARTICLE PREPARED THEREFROM
  申请人：LG CHEM, LTD.

  公开号：EP3778748A1

  公开（公告）日：2021-02-17

  The present invention relates to a nonhalogen flame retardant resin composition having excellent flame retardancy and improved thermal deformation properties, and a flame retardant resin molded article manufactured therefrom, and provides a nonhalogen flame retardant resin composition including a) a base resin including a polyarylene ether-based polymer; an aromatic vinyl-based polymer and a copolymer of vinylcyan monomer-conjugated diene monomer-aromatic vinyl monomer; b) an organophosphorus-based flame retardant; c) a hypophosphite compound; and d) a sulfur-containing compound including at least two sulfur atoms, wherein b) the organophosphorus-based flame retardant, c) the hypophosphite compound and d) the sulfur-containing compound are included in a weight ratio of 15 to 24: 2 to 4: 2 to 5.

  本发明涉及一种具有优异阻燃性和改进热变形性能的无卤阻燃树脂组合物，以及用其制造的阻燃树脂模塑制品，并提供了一种无卤阻燃树脂组合物，该组合物包括 a) 基础树脂，包括聚芳醚基聚合物、芳香族乙烯基聚合物和乙烯基氰单体-共轭二烯单体-芳香族乙烯基单体的共聚物； b) 有机磷基阻燃剂；芳香族乙烯基聚合物和乙烯基氰单体-共轭二烯单体-芳香族乙烯基单体的共聚物；b) 有机磷基阻燃剂；c) 次亚磷酸化合物；和 d) 含硫化合物，包括至少两个硫原子，其中 b) 有机磷基阻燃剂、c) 次亚磷酸化合物和 d) 含硫化合物的重量比为 15 至 24：2至4：2至5。
• SELECTIVE HYDROGENATION CATALYST AND METHODS OF MAKING AND USING SAME
  申请人：Chevron Phillips Chemical Company LP

  公开号：EP2403642A2

  公开（公告）日：2012-01-11