| 937391-36-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 937391-36-1
• 化学式: C₄₅H₄₄N₃P₂Pt*H
• 分子量: 887.876
• InChiKey: HEFBSGMXRIXQLT-BTZAXHLPSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (1,5-cyclooctadiene)dimethylplatinum(II) 、 氘代乙腈 、 N,N'-bis(mesityl)bis(diphenylphosphinoimino)methane 以 氘代乙腈 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Reactivity of an N-mesityl bis(phosphinimino)methane with group 10 metals

  摘要：

  In an attempt to form a group 10 'carbenoid' derivative by double deprotonation of the N-mesityl substituted bis(phosphinimino)methane [CH2(Ph2P=N-2,4,6-Me3C6H2)(2)], reaction with [PdCl2(MeCN)(2)] yielded a singly metallated dichloropalladate(II) complex as the only product. This was completely characterised specroscopically and by single crystal crystal X-ray diffraction. In contrast, reaction of [CH2(Ph2P=N-2,4,6-Me3C6H2)(2)] with [PtMe2(COD)] produced a bis(phosphinimino)methanide complex, which had also undergone ortho-metallation of two P-phenyl groups to effect a triple C-H activation reaction. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.10.020