| 1547296-36-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1547296-36-5
• 化学式: C₅₂H₇₆N₄O₄P₄Rh*Cl
• 分子量: 1083.45
• InChiKey: VPJOOTQXVMESFA-RWJOORBUSA-M

反应信息

• 作为产物：
  描述：

  di(rhodium)tetracarbonyl dichloride 、 、 在 三乙基膦 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Coordination chemistry of bidentate phosphine ligands with hydrogen-bonding arms: Picket-fence rhodium complexes

  摘要：

  A bidentate phosphine ligand with two amide arms, designed to form hydrogen bonds with electron-donating moieties, was synthesized and isolated in high diastereomeric excess (95% de). The hydrogen-bonding abilities of the ligand and its diastereomer were demonstrated with two rhodium complexes containing these ligands. The structures of the rhodium compounds are reminiscent of the well-studied picket-fence porphyrin systems. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.11.018