[ReO2(1,3-bis(diphenylphosphino)propane-P,P')2]I * H2O * CH3OH | 252659-12-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [ReO2(1,3-bis(diphenylphosphino)propane-P,P')2]I * H2O * CH3OH
• CAS: 252659-12-4
• 化学式: CH₄O*C₅₄H₅₂O₂P₄Re*H₂O*I
• 分子量: 1220.07
• InChiKey: ZGSDYESTNKNYQS-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  ammonium perrhenate 、 [ReO2(1,3-bis(diphenylphosphino)propane-P,P')2]I * H2O * CH3OH 以 甲醇 、 二氯甲烷 为溶剂， 生成 [ReO2(1,3-bis(diphenylphosphino)propane-P,P')2]I0.17[ReO4]0.83 * 0.17 H2O * CH3OH
  参考文献：
  名称：

  [ReO₂(dppp)₂]I_x[ReO₄]_1-x^.xH₂O^.CH₃OH forx= 0.17 (1), 0.36 (1) and 1 [dppp is 1,3-bis(diphenylphosphino)propane]

  摘要：

  The crystal structures of [ReO2 (dppp)(2)]I-x[ReO4](1-x).- xH(2)O . CH3OH, where x = 0.17 (1), 0.36 (1) and 1, i.e, dioxo[propane-1,2-diylbis(diphenylphosphine)-P,P']-rhenium iodide perrhenate hydrate methanol solvate, with iodide partially substituted by the perrhenate ion, are described. The compositions studied correspond to x = 0.17(1), 0.36(1) and 1. A solvent water molecule participates in the crystallization in a 1:1 stoichiometric ratio with the iodide ion. The iodide ion and the water molecule together occupy nearly the same space and volume as the perrhenate ion and this facilitates their substitution. The three compositions studied are isostructural and crystallize in space group P2(1)/n. A contraction of the unit cell is detected as the iodide-ion concentration increases.

  DOI：

  10.1107/s0108270199008628
• 作为产物：
  描述：

  、 1,3-双(二苯基膦)丙烷 以 甲醇 、 二氯甲烷 为溶剂， 生成 [ReO2(1,3-bis(diphenylphosphino)propane-P,P')2]I * H2O * CH3OH
  参考文献：
  名称：

  [ReO₂(dppp)₂]I_x[ReO₄]_1-x^.xH₂O^.CH₃OH forx= 0.17 (1), 0.36 (1) and 1 [dppp is 1,3-bis(diphenylphosphino)propane]

  摘要：

  The crystal structures of [ReO2 (dppp)(2)]I-x[ReO4](1-x).- xH(2)O . CH3OH, where x = 0.17 (1), 0.36 (1) and 1, i.e, dioxo[propane-1,2-diylbis(diphenylphosphine)-P,P']-rhenium iodide perrhenate hydrate methanol solvate, with iodide partially substituted by the perrhenate ion, are described. The compositions studied correspond to x = 0.17(1), 0.36(1) and 1. A solvent water molecule participates in the crystallization in a 1:1 stoichiometric ratio with the iodide ion. The iodide ion and the water molecule together occupy nearly the same space and volume as the perrhenate ion and this facilitates their substitution. The three compositions studied are isostructural and crystallize in space group P2(1)/n. A contraction of the unit cell is detected as the iodide-ion concentration increases.

  DOI：

  10.1107/s0108270199008628