trans-[PtI2(3,5-diisopropyl-4-isocyanobenzonitrile)2] | 220721-26-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-[PtI2(3,5-diisopropyl-4-isocyanobenzonitrile)2]
• CAS: 220721-26-6
• 化学式: C₂₈H₃₂I₂N₄Pt
• 分子量: 873.478
• InChiKey: KAWDSWVQGMYKSG-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  3,5-diisopropyl-4-isocyanobenzonitrile 、 platinum(II) iodide 以 二氯甲烷 为溶剂， 以56%的产率得到trans-[PtI2(3,5-diisopropyl-4-isocyanobenzonitrile)2]
  参考文献：
  名称：

  Synthesis and formation of metal complexes of 4-alkynyl and 4-cyano-2,6-diisopropylphenylisocyanides

  摘要：

  The 4-halo-2,6-diisopropyl-N-formyl anilides HC(O)NH-C6H2-i-Pr-2-2,6-X-4, (2a) (X = Br) and 2b (X = I), serve as precursors for the bromo-, iodo -, alkynyl- and cyano- substituted diisopropylphenylisocyanides CN-C6H2-i-Pr-2-2,6-X-4, (3a) (X = Br) and 3b (X = I), CN-C6H2-i-Pr-2-2,6-R-4, (6) (R = C=CSiMe3), (7) (R = C=CH), (9) (R = C=C-C6H4-C=CSiMe3-4), 10 (R = C=C-C6H4-C=CH-4) and 12 (R = CN). The new isocyanides readily form complexes with several metal iodides: CoI2L4, 13 (L = 7), MI2L2, 14-23 (M = Pd and Pt, L = 3a, 3b, 7, 10, 12, and AuIL, 24 and 25 (L = 10 and 12). The crystal structures of the complexes 13, 15 (M = Pt, L = 3a), and 22 (M = Pd, L = 12) have been determined by X-rap crystallography. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00288-6