3,4-epoxycyclohexylmethyl 3',4'-epoxycyclohexanecarboxylate | 37757-92-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: 3,4-epoxycyclohexylmethyl 3',4'-epoxycyclohexanecarboxylate
• 英文别名: 3,4-Epoxycyclohexyl-3,4-epoxycyclo-hexane carboxylate；7-oxabicyclo[4.1.0]heptan-3-yl 7-oxabicyclo[4.1.0]heptane-3-carboxylate
• CAS: 37757-92-9
• 化学式: C₁₃H₁₈O₄
• 分子量: 238.284
• InChiKey: LHFIAMMRYGQCJH-UHFFFAOYSA-N

物化性质

• 沸点：
  348.8±27.0 °C(Predicted)
• 密度：
  1.27±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  51.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-cyclohexenyl 3-cyclohexene-1-carboxylate 在 sodium tungstate (VI) dihydrate 、 氨甲基膦酸 、 二癸基甲胺 硫酸 、 双氧水 作用下， 以 水 为溶剂， 反应 1.0h， 生成 、 、 3,4-epoxycyclohexylmethyl 3',4'-epoxycyclohexanecarboxylate
  参考文献：
  名称：

  EP2261219

  摘要：

  公开号：

文献信息

• Accelerators for cationic photopolymerizations
  申请人：Rensselaer Polytechnic Institute

  公开号：US20030176519A1

  公开（公告）日：2003-09-18

  Compositions that can be photopolymerized by a cationic initiator at an accelerated rate include at least one epoxy monomer, at least one cationic photoinitiator, and a photosensitizer/accelerator. The accelerator is a phenolic resole, or a compound having a structure according to the formula R 1 (CR 2 R 3 OH) n, wherein R 1 is selected from phenyl, polycyclic aryl, and polycyclic heteroaryl, each optionally substituted with one or more electron donating group substituted phenyl; R 2 and R 3 are independently selected from hydrogen, alkyl, aryl, alkylaryl, substituted alkyl, substituted aryl and substituted alkylaryl; and n is an integer from 1 to 10.

  可以通过阳离子引发剂加速光聚合的组分包括至少一种环氧单体、至少一种阳离子光引发剂和一种光敏剂/加速剂。加速剂是酚醛树脂或具有以下结构的化合物R1(CR2R3OH)n，其中R1选自苯基，多环芳基和多环杂芳基，每个选项都可以用一个或多个电子给体取代的苯基替换；R2和R3独立地选自氢，烷基，芳基，烷基芳基，取代烷基，取代芳基和取代烷基芳基；n为1到10的整数。
• Episulfide compound, method for producing the same and optical product comprising the same
  申请人：Hoya Corporation

  公开号：US20030144431A1

  公开（公告）日：2003-07-31

  An episulfide compound useful as a starting material for optical materials that have a high refractive index and a high Abbe's number is provided. A method for producing the same and an optical product made with the same are also provided. The episulfide compound may be represented by the general formula (1): 1 wherein EP represents 2 and n is an integer of from 0 to 2. A method for producing the episulfide compound represented by the general formula (1) may involve reacting a mercapto group-containing episulfide compound with 2,4,6-trimethylene-1,3,5-trithiane.

  提供一种用作光学材料起始物的环氧硫化物化合物，该材料具有高折射率和高阿贝数。同时提供一种制备该化合物的方法以及使用该化合物制作的光学产品。该环氧硫化物化合物可以由一般式（1）表示：其中EP代表2，n为0至2的整数。制备一般式（1）所表示的环氧硫化物化合物的方法可能涉及将含有巯基的环氧硫化物化合物与2,4,6-三亚甲基-1,3,5-三硫杂环己烷反应。
• Polyepoxide curing by polymercaptans plus catalytic co-curing agents
  申请人：DIAMOND SHAMROCK CHEMICALS COMPANY

  公开号：EP0075827A2

  公开（公告）日：1983-04-06

  Extremely rapid ambient curing of polyepoxide resins and mixtures of polyepoxide resins and polyacrylate esters is achieved by use of a curing system composed of at least one polymercaptan and at least one catalytic co-curing agent which is the condensation product of: (a) aliphatic amine or substituted aliphatic amine containing at least one primary aliphatic amine group where the aliphatic moiety is ethylene or greater with (b) at least one amino acid, its corresponding lactam or other amide forming derivative. Optionally, known Lewis Base catalysts for the epoxy/ mercaptan reaction, such as tertiary amines, may also be used.

  通过使用由至少一种聚合物硫醇和至少一种催化助固化剂组成的固化体系，可实现聚环氧树脂以及聚环氧树脂和聚丙烯酸酯混合物的极速常温固化。 催化助固化剂是下列物质的缩合产物：(a) 脂肪族胺或含有至少一个伯脂肪族胺基团的取代脂肪族胺，其中脂肪族分子为乙烯或更大的乙烯基；(b) 至少一种氨基酸、其相应的内酰胺或其他酰胺形成衍生物。 也可选择使用已知的环氧/硫醇反应路易斯碱催化剂，如叔胺。
• Epoxy resins containing bound light stabilizing groups
  申请人：ELF ATOCHEM NORTH AMERICA, INC.

  公开号：EP0507333A2

  公开（公告）日：1992-10-07

  Curable compositions which are precursors for cured or partially cured light stabilized epoxy resins which are the product of the reaction of some or all of the epoxy groups of an epoxy resin with an N-(2,2,6,6-tetraalkyl-4-piperidinyl)amic acid hydrazide as well as the cured or partially cured reaction products thereof together with processes for their use and articles of manufacture produced thereby are disclosed.

  本发明公开了作为固化或部分固化光稳定环氧树脂前体的可固化组合物，这些组合物是环氧树脂的部分或全部环氧基团与 N-(2,2,6,6-四烷基-4-哌啶基)胺酸酰肼反应的产物，以及其固化或部分固化反应产物及其使用工艺和由此生产的制品。
• Hindered-hydroxyl functional (meth)acrylate esters, copolymers containing them and compositions including same
  申请人：UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

  公开号：EP0594109A1

  公开（公告）日：1994-04-27

  This invention relates to hindered-hydroxyl functional (meth)acrylate compounds and derivatives thereof and to processes for the preparation thereof. This invention also relates to hindered-hydroxyl functional (meth)acrylate-containing copolymers and to compositions including same. The hindered-hydroxyl functional (meth)acrylate-containing copolymers have utility in coatings, adhesives, inks, sealants, as well as in other end uses.

  本发明涉及受阻羟基官能团(甲基)丙烯酸酯化合物及其衍生物，以及其制备工艺。本发明还涉及含受阻羟基官能团（甲基）丙烯酸酯共聚物和包括其在内的组合物。含受阻羟基官能团（甲基）丙烯酸酯共聚物可用于涂料、粘合剂、油墨、密封剂以及其他最终用途。