pentacarbonyl{μ-{(η2:η2-ethynyl)benzene}}triphenylphosphinedicobalt-(Co-Co) | 55926-07-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: pentacarbonyl{μ-{(η2:η2-ethynyl)benzene}}triphenylphosphinedicobalt-(Co-Co)
• 英文别名: phenylacetylenepentacarbonyl(triphenylphosphine)dicobalt；phenylacetylenepentacarbonyltriphenylphosphinedicobalt；(μ-PhC*CH)Co2(CO)5(PPh3)；(μ-C6H5H)Co2(CO)5(PPh3)；Carbon monoxide;cobalt;ethynylbenzene;triphenylphosphane
• CAS: 55926-07-3
• 化学式: C₃₁H₂₁Co₂O₅P
• 分子量: 622.465
• InChiKey: VASKUSUGUQPYDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.92
• 重原子数：
  39
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  5
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2,5-二氢呋喃 、 pentacarbonyl{μ-{(η2:η2-ethynyl)benzene}}triphenylphosphinedicobalt-(Co-Co) 以 甲苯 为溶剂， 以8%的产率得到1,3,3a,6a-tetrahydro-5-phenyl-4H-cyclopentafuran-4-one
  参考文献：
  名称：

  The effect of ultrasound and of phosphine and phosphine-oxides on the Khand reaction

  摘要：

  DOI：

  10.1016/0022-328x(88)87050-5
• 作为产物：
  描述：

  (phenylacetylene)hexacarbonyldicobalt 在 三苯基膦 作用下， 以 正己烷 为溶剂， 以45%的产率得到pentacarbonyl{μ-{(η2:η2-ethynyl)benzene}}triphenylphosphinedicobalt-(Co-Co)
  参考文献：
  名称：

  The effect of ultrasound and of phosphine and phosphine-oxides on the Khand reaction

  摘要：

  DOI：

  10.1016/0022-328x(88)87050-5

文献信息

• Paramagnetic organometallic molecules. 13. Electron-transfer-catalyzed reactions of polynuclear metal carbonyls: reactions of R2C2Co2 (CO)6
  作者：Malini Arewgoda、Brian H. Robinson、Jim Simpson

  DOI：10.1021/ja00345a037

  日期：1983.4
• Mild and efficient preparation of alkynepentacarbonyldicobalt complexes containing the chiral (R) -(+) -Glyphos ligand
  作者：William J. Kerr、George G. Kirk、David Middlemiss

  DOI：10.1016/s0022-328x(96)06174-8

  日期：1996.7

  A range of diastereomeric alkynepentacarbonyldicobalt complexes containing the (R)-(+)-Glyphos ligand have been prepared in moderate to good yields under standard thermal conditions. Additionally, novel tertiary amine N-oxide mediated reactions have been developed which allow the synthesis of the same range of complexes at room temperature with good selectivity in consistently high yields. Optically pure (R)-(+)-Glyphos containing complexes have been obtained by preparative HPLC separation of the sets of diastereomeric compounds. Finally, the amine N-oxide techniques allow the rapid and clean preparation of alkynepentacarbonyltriphenylphosphinedicobalt complexes in good to high yields at room temperature.
• The photochemistry of (μ2-RC2H)Co2(CO)6 species (R=H or C6H5), important intermediates in the Pauson–Khand reaction
  作者：Sylvia M. Draper、Conor Long、Bronagh M. Myers

  DOI：10.1016/s0022-328x(99)00374-5

  日期：1999.10
• Preparation of alkynepentacarbonyltriphenylphosphinedicobalt complexes using ultra violet light
  作者：James C. Anderson、Brian F. Taylor、Clare Viney、Graham J. Wilson

  DOI：10.1016/0022-328x(95)06107-x

  日期：1996.7

  The preparation of alkynepentacarbonyltriphenylphosphinedicobalt complexes under mild conditions using linearly polarised ultra violet laser light is described. This method compares favourably with conventional thermal techniques and is superior when the alkyne contains reactive functional groups.