bis(salicylaldehydato)diaquo copper(II) | 283609-43-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(salicylaldehydato)diaquo copper(II)
• 英文别名: bis(salicylaldehydato)diaquocopper(II)；[Cu(sal)2(H2O)2]；copper;2-formylphenolate;dihydrate
• CAS: 283609-43-8
• 化学式: C₁₄H₁₄CuO₆
• 分子量: 341.808
• InChiKey: HIQBKRVJGXUPRF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  2,2'-二吡啶胺 、 bis(salicylaldehydato)diaquo copper(II) 以 not given 为溶剂， 以87.35%的产率得到bis(salicylaldehydato)(2,2'-bipyridylamine)copper(II) monohydrate
  参考文献：
  名称：

  Synthesis, Characterization and Antimicrobial Activities of Some Transition Metal Complexes Containing Two Bidentate (O-O) Monobasic Hydroxy Aldehydes and 2,2′-Bipyridylamine

  摘要：

  The mixed-ligand complexes of Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) with 2,2'-bipyridylamine and salicylaldehyde or 5-chlorosalicylaldehyde were prepared and characterized on the basis of elemental analyses, magnetic measurements, infrared spectra, electronic spectra and thermogravimetric analyses. The antimicrobial activities of the complexes were tested against bacteria. An octahedral geometry has been assigned to all the prepared complexes.

  DOI：

  10.1080/00945710009351802

文献信息

• Synthesis, Characterization, and Biocidal Studies of Some Transition Metal Complexes Containing Bidentate Monobasic Hydroxyaldehydes and a Neutral Bidentate Schiff Base
  作者：M. N. Patel、N. H. Patel、K. N. Patel、P. P. Dholakiya、D. H. Patel

  DOI：10.1081/sim-120016872

  日期：2003.1.3

  Complexes of the transition metals with salicylaldehyde (sa1H) or 5-bromosalicylaidehyde (Br-sa1H) in 1:2 molar ratio, have the compositions [M(H2O)(2)(sal)(2)](H2O)-H-. (1) or [M(H2O)(2)(Br-sal)(2)](H2O)-H-. (2), respectively. The Schiff base derived from ethylenediamine and benzaldehyde in 1:1 molar ratio in alcoholic solution yields bis(benzylidene)ethylenediamine (benen). Further reaction of (1) or (2) with benen in alcohol yielded mixed-ligand complexes of the type [M(sal)(2)benen] or [M(Br-sal)(2)benen], respectively. All of these complexes are soluble in ethanol and methanol.
• Synthesis, Spectral, and Biocidal Studies of Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) Mixed‐Ligand Complexes
  作者：M. N. Patel、N. H. Patel、P. K. Panchal、D. H. Patel

  DOI：10.1081/sim-120037513

  日期：2004.5

  Complexes of transition metals with salicylaldehyde (saIH) or 5-bromosalicylaldehyde (Br-salH) in I : 2 molar ratio, have the compositions [M(H2O)(2)(sal)(2)] . H2O (1) or [M(H2O)(2)(Br-sal)(2)] . H2O (2), respectively. The Schiff base derived from ethylenediamine and acetophenone in I : I molar ratio in alcoholic solution yields his(acetophenone)ethylenediamine (acphen). Further reaction of (1) or (2) with acphen in alcohol yielded mixed-ligand complexes of the type [M(sal)(2)acphen] or [M(Br-sal)(2) acphen], respectively. All of these complexes are Soluble in ethanol and methanol. They were characterized on the basis of elemental analyses, magnetic measurements, infrared spectra, electronic spectra, and thermogravimetric analyses. All of these complexes have been screened for their antimicrobial activity against bacteria] strands using the agar diffusion method.