Graft polyester products, method of sizing yarns therewith and a synthetic fiber sized with such graft polyester products
申请人:BASF WYANDOTTE CORPORATION
公开号:EP0010582A2
公开(公告)日:1980-05-14
There are disclosed graft polyesters useful as adhesives and coatings and especially useful in processes for sizing spun and continous filament synthetic organic and inorganic fibrous yarn. One embodiment of the invention is a textile size composition having free carboxyl groups which is prepared in situ on a textile yarn by the application of heat or radiation to a mixture of an unsaturated polyester reactant and a monovinyl monomer reactant comprising an acidic monovinyl monomer having at least one carboxyl group or mixtures thereof with any monovinyl monomer.
Desizing can be accomplished by partial neutralization of the size to a pH of at least 6 by reacting the size with a base to render the graft polyester water-dispersible or water-soluble.
Also disclosed are cross-linked graft polyesters obtained by reacting an unsaturated polyester with at least one polyunsaturated vinyl monomer.
本发明公开了可用作粘合剂和涂料的接枝聚酯,尤其适用于纺丝和连续长丝合成有机和无机纤维纱线的上浆工艺。本发明的一个实施方案是一种具有游离羧基的纺织品上浆组合物,它是通过对不饱和聚酯反应物和单乙烯基单体反应物的混合物进行加热或辐射而在纺织纱线上就地制备的,不饱和聚酯反应物和单乙烯基单体反应物包括具有至少一个羧基的酸性单乙烯基单体或其与任何单乙烯基单体的混合物。
通过与碱反应,使接枝聚酯具有水分散性或水溶性,从而将尺寸部分中和至 pH 值至少为 6,从而达到退浆的目的。
还公开了通过不饱和聚酯与至少一种多不饱和乙烯基单体反应而获得的交联接枝聚酯。