[Co(κ2-N3, S-C7H8N3OS)3] | 1415313-71-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: [Co(κ2-N3, S-C7H8N3OS)3]
• CAS: 1415313-71-1
• 化学式: C₂₁H₂₄CoN₉O₃S₃
• 分子量: 605.671
• InChiKey: OXDVORDSSDTADC-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-furaldehyde-4-methylthiosemicarbazone 、 cobalt(II) chloride hexahydrate 在 三乙胺 作用下， 以 甲苯 为溶剂， 反应 2.25h， 以65%的产率得到[Co(κ2-N3, S-C7H8N3OS)3]
  参考文献：
  名称：

  Metal derivatives of N1-substituted thiosemicarbazones: Synthesis, structures and spectroscopy of nickel(II) and cobalt(III) complexes

  摘要：

  Reactions of nickel(II) and cobalt(II) salts with various N-1-substituted thiosemicarbazones [(RRC2)-R-1-C-2=N-3-(NH)-H-2-C-1(=S)-(NHR3)-H-1, (HL)-L-2; R-1 = C6H5-, R-2 = H, H2L1(R-3 = Me); H2L2(R-3 = Ph), R-1 = 2-OHC6H4-, R-2 = H, H2L3(R-3 = Me), H2L4(R-3 = Et), H2L5(R-3 = Ph); R-2 = Me, H2L6(R-3 = Me), R-2 = Me, H2L7(R-3 = Et) and R-2, R-3 = H, Me, H2L8(R-1 = C4H3S), H2L9(R-1 = C4H3O)] are described. Reactions of Ni(OAc)(2) with the ligands having R-1 as phenyl group at C-2 carbon (H2L1, H2L2) gave complexes, [Ni(kappa(2)-N-3, S-HL)(2)] (HL = HL1, 1; HL2, 2). Other ligands with R-1 as 2-hydroxyphenyl groups, namely, H2L3-H2L7, with Ni(OAc)(2) yielded rust colored compounds, {Ni(kappa(3)-O, N-3, S-L)} (L-2 = L-3-L-7) which after the addition of PPh2-CH2-PPh2 yielded dinuclear, [Ni-2(kappa(3)-O, N-3, S-L)(2)(mu-P, P-PPh2-CH2-PPh2)] (L-2 = L-3, 3; L-4, 4; L-5, 5) and mononuclear, [Ni(kappa(3)-O, N-3, S-L)(kappa(1)-P-PPh2-CH2-PPh2)] (L-2 = L-6, 6; L-7, 7) complexes. Likewise, {Ni(kappa(3)-O, N-3, S-L-5} with 2-phenylpyridine(2-Phpy) has yielded a mononuclear complex, [Ni(kappa(3)-O, N-3, S-L-5)(kappa(1)-N-2-Phpy)] 8. The geometry around Ni metal center can be formally described as square planar in each of complexes 1-8. Reactions of CoCl2 with H2L8 and H2L9 involved oxidation of Co-II to Co-III and yielded octahedral complexes, [Co(kappa(2)-N, S-HL)(3)] (HL = HL8, 9; HL9, 10). (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.09.021