2,5-bis(2'-(1'',2'',3'',4'',5''-pentamethylruthenocenyl)ethenyl)thiophene | 1007403-71-5

• 英文名称: 2,5-bis(2'-(1'',2'',3'',4'',5''-pentamethylruthenocenyl)ethenyl)thiophene
• CAS: 1007403-71-5
• 化学式: C₃₈H₄₄Ru₂S
• 分子量: 734.973
• InChiKey: PGSDSZBFTPVGMC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ferrocenium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate 、 2,5-bis(2'-(1'',2'',3'',4'',5''-pentamethylruthenocenyl)ethenyl)thiophene 以 N,N-二甲基乙酰胺 为溶剂， 以98%的产率得到[(C₅(CH₃)5)Ru(C₅H₄CHCH)]2C₄H₂S⁽²⁺⁾*2B(C₆H₃(CF₃)2)4^(1-)=[(C₅(CH₃)5)Ru(C₅H₄CHCH)]2C₄H₂S[B(C₆H₃(CF₃)2)4]2
  参考文献：
  名称：

  Synthesis and some properties of binuclear ruthenocene derivatives bridged by both ethene and thiophene derivatives

  摘要：

  Binuclear ruthenocenes bridged by ethenes and thiophene derivatives, Rc-CH=CH-Z-Rc and Rc*-CH=CH-Z CH=CH-Rc* (Z = thiophene, thieno[3,2-b]thiophene, and 2,2'-bithiophene; Rc = ruthenocenyl, R* = 1',2',3',4',5'-pentamethylruthenocenyl) were prepared. These complexes showed a one-step two-electron redox wave in the cyclic voltammograms, in contrast to the benzenoid-bridged dinuclear ruthenocenes. The chemical oxidation of the Rc-CH=CH-Z-Rc complexes gave no stable oxidized species. The two-electron oxidized species of the Rc*-CH=CH-Z-CH=CH-Rc* complexes were comparably stable and contained a fulvene-complex type structure. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.07.057
• 作为产物：
  描述：

  2,5-噻吩二甲醛 、 (1'',2'',3'',4'',5''-pentamethylruthenocenylmethyl)triphenylphosphonium bromide 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 为溶剂， 以43%的产率得到2,5-bis(2'-(1'',2'',3'',4'',5''-pentamethylruthenocenyl)ethenyl)thiophene
  参考文献：
  名称：

  Synthesis and some properties of binuclear ruthenocene derivatives bridged by both ethene and thiophene derivatives

  摘要：

  Binuclear ruthenocenes bridged by ethenes and thiophene derivatives, Rc-CH=CH-Z-Rc and Rc*-CH=CH-Z CH=CH-Rc* (Z = thiophene, thieno[3,2-b]thiophene, and 2,2'-bithiophene; Rc = ruthenocenyl, R* = 1',2',3',4',5'-pentamethylruthenocenyl) were prepared. These complexes showed a one-step two-electron redox wave in the cyclic voltammograms, in contrast to the benzenoid-bridged dinuclear ruthenocenes. The chemical oxidation of the Rc-CH=CH-Z-Rc complexes gave no stable oxidized species. The two-electron oxidized species of the Rc*-CH=CH-Z-CH=CH-Rc* complexes were comparably stable and contained a fulvene-complex type structure. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.07.057