2-ethyliminomethyl-4-methyl-6-([methyl-(2-pyridin-2-yl-ethyl)amino]methyl)phenol | 618885-17-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-ethyliminomethyl-4-methyl-6-([methyl-(2-pyridin-2-yl-ethyl)amino]methyl)phenol
• 英文别名: 2-(Ethyliminomethyl)-4-methyl-6-[[methyl(2-pyridin-2-ylethyl)amino]methyl]phenol
• CAS: 618885-17-9
• 化学式: C₁₉H₂₅N₃O
• 分子量: 311.427
• InChiKey: MMRLIEUNKJIWLP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  23
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  48.7
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-ethyliminomethyl-4-methyl-6-([methyl-(2-pyridin-2-yl-ethyl)amino]methyl)phenol 、 sodium thiocyanide 、 cobalt(II) diacetate tetrahydrate 以 甲醇 为溶剂， 以21%的产率得到Co3(2-ethyliminomethyl-4-methyl-6-([methyl-(2-pyridin-2-yl-ethyl)amino]methyl)phenolate)2(OAc)2(NCS)2*H2O
  参考文献：
  名称：

  The structures and magnetism of trinuclear Ni(II), Co(II) and Mn(II) complexes derived from unsymmetrical compartmental ligands

  摘要：

  Trinuclear Ni(II), Co(II) and Mn(II) complexes have been prepared from the asymmetric compartmental proligands 2-alkyliminomethyl-4-methyl-6-{[methyl-(2-pyridin-2-yl-ethyl)-amino]-methyl}-phenol(alkyl = ethyl, n-propyl and n-butyl) and 2-[(2methoxy-ethylimino)-methyl]-4-methyl-6-{[methyl-(2-pyridin-2-yl-ethyl)-amino]-methyl} -phenol, which provide adjacent tridentate N2O and bidentate NO donor sets. The crystal structures of [Ni-3(L-6)(2)(OAc)(2)(NCS)(2)] . CH3OH . H2O, [Co-3(L-4)(2)(OAc)(2)(NCS)(2)], and [Mn-3(L-7)(2)(OAc)(2)(NCS)(2)] . CH3OH . H2O were determined and show that the metals provide an isosceles triangle with M-1-M-2=M-1-M-3 approximate to 3.2 Angstrom and M-2-M-3 approximate to 5.0 Angstrom. The cryomagnetic properties of the complexes have been studied and indicate a weak antiferromagnetic interaction between the adjacent, (MM2)-M-1 and (MM3)-M-1 ions with little magnetic interaction between the terminal (MM3)-M-2 ions. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.03.055

文献信息

• Copper(II) complexes of unsymmetric compartmental ligands bearing adjacent {N2O}, {N,S,O} donor sets and {N2O}, {N,O} donor sets
  作者：Harry Adams、Scott Clunas、Laura R. Cummings、David E. Fenton、Paul E. McHugh

  DOI：10.1016/s1387-7003(03)00118-7

  日期：2003.7

  The unsymmetric compartmental proligands HL2, HL5 and HL6 bearing adjacent N2O}, N,S,O} donor sets and N2O}, N,O} donor sets have given the dinuclear copper (II) complexes [Cu-2(L-2) (OMe)(NCS)(2)], 1, [Cu-2(L-5)(OMe)(NCS)(2)], 2, and [Cu-2(L-6)(OMe)(NCS)(2)], 3. The crystal structures of these complexes are reported. (C) 2003 Elsevier Science B.V. All rights reserved.