| 93625-14-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• CAS: 93625-14-0
• 化学式: C₂F₅O
• 分子量: 135.013
• InChiKey: SKQFZBKPXBDELV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  乙烯 、 以 正庚烷 为溶剂， 反应 0.33h， 生成
  参考文献：
  名称：

  Komendantov, A. M.; Sass, V. P.; Sokolov, S. V., Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, p. 439 - 441

  摘要：

  DOI：
• 作为产物：
  描述：

  五氟二甲基醚 在 氯 作用下， 21.85 ℃ 、93.33 kPa 条件下， 反应 1.0h， 生成
  参考文献：
  名称：

  Atmospheric degradation mechanism of CF3OCF2H

  摘要：

  Smog chamber/FTIR techniques were used to study the Cl atom initiated oxidation of CF3OCF2H in 700 Torr of N-2/O-2 at 295 +/- 2 K. Atmospheric oxidation of CF3OCF2H proceeds via the formation of CF3OCF2 radicals. The atmospheric fate of CF3OCF2 radicals is addition Of O-2 to give CF3OCF2O2 radicals. In the atmosphere CF3OCF2O, radicals are converted via COF2 and CF3OH into CO2 and HF. Relative rate techniques were used to measure k(Cl + CF3OCF2H) = (2.3 +/- 0.3) x 10(-17) cm(3) molecule(-1) s(-1). The results are discussed with respect to the atmospheric degradation and environmental impact of CF3OCF2H. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0009-2614(01)00698-4

文献信息

• Komendantov, A. M.; Sass, V. P.; Sokolov, S. V., Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, p. 439 - 441
  作者：Komendantov, A. M.、Sass, V. P.、Sokolov, S. V.

  DOI：——

  日期：——
• Atmospheric degradation mechanism of CF3OCF2H
  作者：Y. Inoue、M. Kawasaki、T.J. Wallington、M.D. Hurley

  DOI：10.1016/s0009-2614(01)00698-4

  日期：2001.8

  Smog chamber/FTIR techniques were used to study the Cl atom initiated oxidation of CF3OCF2H in 700 Torr of N-2/O-2 at 295 +/- 2 K. Atmospheric oxidation of CF3OCF2H proceeds via the formation of CF3OCF2 radicals. The atmospheric fate of CF3OCF2 radicals is addition Of O-2 to give CF3OCF2O2 radicals. In the atmosphere CF3OCF2O, radicals are converted via COF2 and CF3OH into CO2 and HF. Relative rate techniques were used to measure k(Cl + CF3OCF2H) = (2.3 +/- 0.3) x 10(-17) cm(3) molecule(-1) s(-1). The results are discussed with respect to the atmospheric degradation and environmental impact of CF3OCF2H. (C) 2001 Elsevier Science B.V. All rights reserved.