Hg(C6H2-2,3-(OCH2O)-6-CH2NMe2)2 | 167031-63-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并间二氧杂环戊烯类
• 英文名称: Hg(C6H2-2,3-(OCH2O)-6-CH2NMe2)2
• 英文别名: Hg(C6H2(OCH2O)-2,3-CH2NMe2-6)2
• CAS: 167031-63-2
• 化学式: C₂₀H₂₄HgN₂O₄
• 分子量: 557.012
• InChiKey: HMZRITCLLRXOQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [((η(5)-C5H5)Mo(μ-I)(I)(NO))2] 、 Hg(C6H2-2,3-(OCH2O)-6-CH2NMe2)2 以 二氯甲烷 为溶剂， 以95%的产率得到[(η(5)-C5H5)Mo(C6H2-(OCH2O)-2,3-CH2NMe2-6)(I)(NO)]
  参考文献：
  名称：

  Synthesis and characterization of asymmetric C,N-cyclometallated complexes of Mo(II). X-ray crystal structures of [η5-C5H5)MoC6H2-(OCH2O)-2,3-CH2NMe2-6(I)(NO)] and [(η5-C5H5)MoS-C6H4CH(Me)NMe2-2(I)(NO)]

  摘要：

  The reaction of {(eta(5)-C5H5)Mo(mu-I)(I)(NO)}(2)] with the Hg derivatives of substituted N,N-dimethylbenzylamines [Hg(Q dmba)(2)] (HQ = substituted N,N-dimethylbenzylamine affords the organomolybdenum complexes [(eta(5)-C5H5)Mo(Qdmba)(I)(NO)] (2a-2e) in nearly quantitative yield as a racemic mixture of both enantiomers. When the reaction is carried out with Hg{S-C6H4C(H)(Me)NMe(2)}(2), a 1:1 mixture of both diastereoisomers [(eta(5)-C5H5)Mo{S-C6H4C(H)(Me)NMe(2)-2}(I)(NO)] (2f-2g) is obtained. The resolution of this mixture can be accomplished by fractional crystallization in CH2Cl2/hexane. The X-ray crystal structure of the complexes (SPY-5-15-A,C)-[(eta(5)-C5H5)Mo{C6H2-(OCH2O)-2,3-CH(2)NMe(2)-6}(I)(NO)] (2b) and (SPY-5-15-C)-[(eta(5)-C5H5)Mo{S-C6H4C(H)(Me)NMe(2)-2}(I)(NO)] (2f) are reported.

  DOI：

  10.1016/0022-328x(95)05429-s
• 作为产物：
  描述：

  1-(苯并[d][1,3]二氧代l-5-基)-N,N-二甲基甲胺 、 mercury dichloride 在 BuLi 作用下， 以 乙醚 为溶剂， 以74%的产率得到Hg(C6H2-2,3-(OCH2O)-6-CH2NMe2)2
  参考文献：
  名称：

  Synthesis and characterization of asymmetric C,N-cyclometallated complexes of Mo(II). X-ray crystal structures of [η5-C5H5)MoC6H2-(OCH2O)-2,3-CH2NMe2-6(I)(NO)] and [(η5-C5H5)MoS-C6H4CH(Me)NMe2-2(I)(NO)]

  摘要：

  The reaction of {(eta(5)-C5H5)Mo(mu-I)(I)(NO)}(2)] with the Hg derivatives of substituted N,N-dimethylbenzylamines [Hg(Q dmba)(2)] (HQ = substituted N,N-dimethylbenzylamine affords the organomolybdenum complexes [(eta(5)-C5H5)Mo(Qdmba)(I)(NO)] (2a-2e) in nearly quantitative yield as a racemic mixture of both enantiomers. When the reaction is carried out with Hg{S-C6H4C(H)(Me)NMe(2)}(2), a 1:1 mixture of both diastereoisomers [(eta(5)-C5H5)Mo{S-C6H4C(H)(Me)NMe(2)-2}(I)(NO)] (2f-2g) is obtained. The resolution of this mixture can be accomplished by fractional crystallization in CH2Cl2/hexane. The X-ray crystal structure of the complexes (SPY-5-15-A,C)-[(eta(5)-C5H5)Mo{C6H2-(OCH2O)-2,3-CH(2)NMe(2)-6}(I)(NO)] (2b) and (SPY-5-15-C)-[(eta(5)-C5H5)Mo{S-C6H4C(H)(Me)NMe(2)-2}(I)(NO)] (2f) are reported.

  DOI：

  10.1016/0022-328x(95)05429-s

文献信息

• Importance of steric effects upon the synthesis of {(η6-arene)RuCl}-C,N-cyclometallated amines
  作者：Michel Pfeffer、Jean-Pascal Sutter、Esteban P. Urriolabeitia

  DOI：10.1016/0020-1693(96)05030-x

  日期：1996.8

  Abstract The transmetallation reaction between [( η 6 -arene)RuCl 2 ] 2 ( η 6 -arene = C 4 H 6 (benzene) ( 1 ); 1-Me-4- 1 Pr-C 6 H 4 (cymene) ( 2 ); 1,2,4,5-Me 4 -C 6 H 2 (durene) ( 3 ); 1,2,3,5-Me 4 -C 6 H 2 (isodurene) ( 4 ) and the aminoaryl-mercury derivatives HgQ-dmba} 2 (Q-dmba = 1-C 6 H 3 -3-F-6-CH 2 NMe 2 } ( a ); 1-C 6 H 3 -6-CH 2 NMe 2 } ( b ); 1-C 6 H 2 -2,3-OCH 2 OCH 2 -6-CH 2 NMe 2

  摘要[（η6-芳烃）RuCl 2] 2（η6-芳烃= C 4 H 6（苯）（1）; 1-Me-4- 1 Pr-C 6 H 4（苏木）（ 2）; 1,2,4,5-Me 4 -C 6 H 2（二烯）（3）; 1,2,3,5-Me 4 -C 6 H 2（异二烯）（4）和氨基芳基-汞衍生物Hg Q-dmba} 2（Q-dmba = 1- C 6 H 3 -3-F-6-CH 2 NMe 2}（a）; 1- C 6 H 3 -6-CH 2 NMe 2}（b）; 1- C 6 H 2 -2,3-OCH 2 OCH 2 -6-CH 2 NMe 2}（c）1- C 6 H02,4-（MeO）2 -6-CH 2 NMe 2}（b）; 1- C 6 H 4 CH 2 NMe 2}（e）得到相应的C，N-环钌化的配合物[η6-芳烃）RuCl Q-dmba}。通过1 H和13 C 1 H} NMR进