S,S'-(diphenylstannylene) O,O,O',O'-tetraphenyl bis(phosphorodithioate) | 78740-25-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: S,S'-(diphenylstannylene) O,O,O',O'-tetraphenyl bis(phosphorodithioate)
• CAS: 78740-25-7
• 化学式: C₃₆H₃₀O₄P₂S₄Sn
• 分子量: 835.553
• InChiKey: JADSILCPGBJHFX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  10.47
• 重原子数：
  47
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.9
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  S,S'-(diphenylstannylene) O,O,O',O'-tetraphenyl bis(phosphorodithioate) 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 以60%的产率得到diphenoxythioxaphosphoranesulfenyl bromide
  参考文献：
  名称：

  Thiophosphorosulfenyl bromides and iodides — synthesis and characterization

  摘要：

  DOI：

  10.1016/s0040-4039(00)96891-6

文献信息

• The First Synthesis and Isolation of ‘Bis(aryloxy)phosphorothioylsulfenyl Iodides' (=Bis(aryloxy)phosphinesulfenyl Iodide P-Sulfides) from the Reaction of S,S′-(Diphenylstannylene) O,O,O′,O′-Tetraaryl Bis[phosphorodithioates] (=[(Diphenylstannylene)bis(thio)]bis[bis(aryloxy)phosphine P-Sulfides]) with N-Iodosuccinimide
  作者：Min Shi、Shinji Kato

  DOI：10.1002/1522-2675(200208)85:8<2559::aid-hlca2559>3.0.co;2-9

  日期：2002.8

  S,S'-(Diphenylstannylene) O,O,O',O'-tetraaryl bis[phosphorodithioates] (= [(diphenylstannylene)bis(thio)]bis[bis(aryloxy)phosphine P-sulfides]) 5 react with N-iodosuccinimide (NIS) in CH2Cl2 at -30degrees under A to give 'bis(aryloxy)phosphorothioylsulfenyl iodides' (=bis(aryloxy)phosphinesulfenyl iodide P-sulfides) 6 (Scheme 3), which can readily react in situ with 4-methylbenzenecarbodithioic acid, thiol, and cyclohexene to afford the corresponding unsymmetrical disulfides and the adduct in good yields as the novel electrophilic dithiophosphorylating reagents (Schemes 4 and 5). By adding hexane into the solution at -30degrees after reaction of 5 with NIS, the 'phosphorothioylsulfenyl iodides' 6 can be isolated as yellow solids in good yields (see Table).
• KATO, SHINZI;MIN, SHI;BENIYA, YASUFUMI;ISHIDA, MASARU, TETRAHEDROM LETT., 28,(1987) N 51, 6473-6474
  作者：KATO, SHINZI、MIN, SHI、BENIYA, YASUFUMI、ISHIDA, MASARU

  DOI：——

  日期：——
• Thiophosphorosulfenyl bromides and iodides — synthesis and characterization
  作者：Shinzi Kato、Shi Min、Yasufumi Beniya、Masaru Ishida

  DOI：10.1016/s0040-4039(00)96891-6

  日期：1987.1