| 404594-45-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 404594-45-2
• 化学式: C₅₀H₇₂P₂
• 分子量: 735.069
• InChiKey: XTAKERHWUBOGLU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.1
• 重原子数：
  52
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  生成 (E,E)-1,2-dipent-4-ynyl-3,4-bis[(2,4,6-tri-t-butylphenyl)phosphindene]cyclobutene
  参考文献：
  名称：

  Preparation of Sterically Protected 3,4-Bis[(2,4,6-tri-tert-butylphenyl)phosphinidene]cyclobutene Derivatives Having Ring-Fused Structures

  摘要：

  Sterically protected 3,4-diphosphinidenecyclobutenes, having ring-fused structures, were prepared. Structures of 8,9-bis[(2,4,6-tri-tert butylphenyl)phosphinidene]bicyclo[5.2.0]non-1(7)-ene and its dichloropalladium(II) complex were analyzed by X-ray crystallography. A geometrical change induced by the complex formation was exhibited by X-ray crystallographic analysis. The geometrical change in solution was also suggested by H-1 NMR spectroscopy in CDCl3.

  DOI：

  10.1021/ol017169h
• 作为产物：
  描述：

  (2,4,6-三-叔-丁基苯基)膦 在 偶氮二异丁腈 、 potassium carbonate 作用下， 以 四氯化碳 为溶剂， 反应 1.0h， 生成
  参考文献：
  名称：

  Preparation of Sterically Protected 3,4-Bis[(2,4,6-tri-tert-butylphenyl)phosphinidene]cyclobutene Derivatives Having Ring-Fused Structures

  摘要：

  Sterically protected 3,4-diphosphinidenecyclobutenes, having ring-fused structures, were prepared. Structures of 8,9-bis[(2,4,6-tri-tert butylphenyl)phosphinidene]bicyclo[5.2.0]non-1(7)-ene and its dichloropalladium(II) complex were analyzed by X-ray crystallography. A geometrical change induced by the complex formation was exhibited by X-ray crystallographic analysis. The geometrical change in solution was also suggested by H-1 NMR spectroscopy in CDCl3.

  DOI：

  10.1021/ol017169h

文献信息

• Preparation of Sterically Protected 3,4-Bis[(2,4,6-tri-<i>tert</i>-butylphenyl)phosphinidene]cyclobutene Derivatives Having Ring-Fused Structures
  作者：Naoki Yamada、Keita Abe、Kozo Toyota、Masaaki Yoshifuji

  DOI：10.1021/ol017169h

  日期：2002.2.1

  Sterically protected 3,4-diphosphinidenecyclobutenes, having ring-fused structures, were prepared. Structures of 8,9-bis[(2,4,6-tri-tert butylphenyl)phosphinidene]bicyclo[5.2.0]non-1(7)-ene and its dichloropalladium(II) complex were analyzed by X-ray crystallography. A geometrical change induced by the complex formation was exhibited by X-ray crystallographic analysis. The geometrical change in solution was also suggested by H-1 NMR spectroscopy in CDCl3.