[Fe(EtioPc)(tBuNC)2]ClO4 | 1360463-63-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: [Fe(EtioPc)(tBuNC)2]ClO4
• CAS: 1360463-63-3
• 化学式: C₄₂H₅₄FeN₆*ClO₄
• 分子量: 798.229
• InChiKey: QCKIVTQNXZXEHS-WTXRTFJCSA-M

反应信息

• 作为产物：
  描述：

  bis(tetrahydrofuran)(3,6,13,16-tetraethyl-2,7,12,17-tetramethylporphycenato)iron(III) perchlorate 、 异氰酸叔丁酯 以 二氯甲烷 为溶剂， 生成 [Fe(EtioPc)(tBuNC)2]ClO4
  参考文献：
  名称：

  Unusual electronic structure of bis-isocyanide complexes of iron(iii) porphyrinoids

  摘要：

  A series of isocyanide complexes, [Fe(Porphyrinoid)(tBuNC)2]+, were synthesized and examined for their physicochemical properties. The molecular structure of the bis(tBuNC) adduct of the iron(III) porphycene (1) and corrphycene (2) adopting the (dxy)2(dxz, dyz)3 ground state were determined for the first time. Furthermore, 1 and 2 showed unusual crossover phenomena between different electron configurations, (dxy)2(dxz, dyz)3 ground state and (dxz, dyz)4(dxy)1 ground state, by the addition of the external stimuli.

  DOI：

  10.1039/c2dt12249a