(meso-tetrakis(1-methyl-4-pyridinio)porphyrin)bis(pyridin)ruthenium(II)(4+) | 350484-15-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (meso-tetrakis(1-methyl-4-pyridinio)porphyrin)bis(pyridin)ruthenium(II)(4+)
• CAS: 350484-15-0
• 化学式: C₅₄H₄₆N₁₀Ru
• 分子量: 936.096
• InChiKey: RMWMIKIDWUJRON-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  (5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrinato)cobalt(II) 、 (meso-tetrakis(1-methyl-4-pyridinio)porphyrin)bis(pyridin)ruthenium(II)(4+) 以 甲醇 、 水 为溶剂， 生成 [(meso-tetrakis(4-sulfonatophenyl)porphyrin)cobalt(II)][(meso-tetrakis(1-methyl-4-pyridinio)porphyrin)ruthenium(II)]
  参考文献：
  名称：

  Electroreduction of Dioxygen Using Co–Ru Dinuclear Porphyrin Catalyst in Nafion Film

  摘要：

  The mixing of CoTPPS with RuTMPyP (Figure 1) in water or organic solvents (DMSO, acetonitrile) results in dimerization through an electrostatic interaction. The dimeric porphyrin acts as an excellent catalyst for the 4-electron reduction of dioxygen in Nafion film, in which the multi-electron transfer is accelerated through the π-orbital overlapping.

  DOI：

  10.1246/cl.2001.412