| 289907-86-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 289907-86-4
• 化学式: C₂₈H₃₂N₂NiO₂P₄S₂
• 分子量: 675.291
• InChiKey: VTUKUFILQLAWIK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 potassium P,P-dimethyl-P',P'-diphenyl-P-thioimidodiphosphiniate 以 甲醇 为溶剂， 以73%的产率得到
  参考文献：
  名称：

  First nickel(II) complexes containing tetrahedral NiO2S2 cores. The molecular structures of Ni[(OPPh2)(SPR2)N]2 (R=Ph, Me)

  摘要：

  Ni[(OPR2')(SPR2)N](2), complexes were obtained in good yields by reacting NiCl2. 6H(2)O and the alkaline salts of the corresponding tetraorganomonothioimidodiphosphinic acids. All compounds were characterized by elemental analysis and IR. The molecular structure of Ni[(OPPh2)(SPR2)N](2), (R=Ph, Me) has been determined by single-crystal X-ray diffractometry. Ni[(OPPh2)-(SPPh2)N](2) (1) crystallizes in the monoclinic space group P2(l)/c (no. 14), and Ni[(OPPh2)(SPMe2)N](2) (2) crystallizes in the triclinic space group P1 (no. 2). The crystals of both compounds contain discrete mononuclear molecules. The asymmetric ligands act as monometallic biconnective units which results in a tetrahedral NiO2S2 core. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00118-3