(3-Iodo-2-methoxypropyl)benzene | 86151-58-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (3-Iodo-2-methoxypropyl)benzene
• CAS: 86151-58-8
• 化学式: C₁₀H₁₃IO
• 分子量: 276.117
• InChiKey: XPPOKPZWASAJHY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  烯丙苯 、 甲醇 以42%的产率得到
  参考文献：
  名称：

  SATO, TADASHI;TAMURA, KUNIO;NAGAYAOSHI, KAZUO, CHEM. LETT., 1983, N 5, 791-794

  摘要：

  DOI：

文献信息

• A CONVENIENT SYNTHETIC METHOD OF 1,3-DISUBSTITUTED ISOQUINOLINES USING SILVER TRIFLUOROMETHANESULFONATE AS A KEY REAGENT
  作者：Tadashi Sato、Kunio Tamura、Kazuo Nagayoshi

  DOI：10.1246/cl.1983.791

  日期：1983.5.5

  1,3-Disubstituted isoquinolines were prepared under mild conditions from allylbenzenes and nitriles using silver trifluoromethanesulfonate and iodine.

  1,3-二取代异喹啉是在温和条件下，使用三氟甲磺酸银和碘从烯丙基苯和腈制备的。
• m-Iodosylbenzoic acid, a tagged hypervalent iodine reagent for the iodo-functionalization of alkenes and alkynes
  作者：Mekhman S. Yusubov、Roza Ya. Yusubova、Andreas Kirschning、Joo Yeon Park、Ki-Whan Chi

  DOI：10.1016/j.tetlet.2007.12.120

  日期：2008.2

  An efficient and facile method for the iodo-functionalization of alkenes 5 and alkynes 6 by using recyclable ni-iodosylbenzoic acid (2) was developed. The final products can be easily isolated without any chromatographic purification by simple treatment of the crude mixture with an anionic exchange resin. Unreacted m-iodosylbenzoic acid and reduced m-iodobenzoic acid are effectively recovered from the resin by acidification with hydrochloric acid. (c) 2008 Elsevier Ltd. All rights reserved.