2-(methylthio)pentafluoropropene | 169138-13-0

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: 2-(methylthio)pentafluoropropene
• 英文别名: 1,1,3,3,3-pentafluoro-2-methylsulfanylprop-1-ene
• CAS: 169138-13-0
• 化学式: C₄H₃F₅S
• 分子量: 178.126
• InChiKey: GCBYUPZUVQHSTK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-(methylthio)pentafluoropropene 在 六甲基二硅氮烷 作用下， 反应 8.0h， 以60%的产率得到2-methylthio-2H-trifluoropropionitrile
  参考文献：
  名称：

  2-(Methylthio)pentafluoropropene

  摘要：

  2-(Methylthio) pentafluoropropene was obtained by dehydrofluorination of methyl 2H-hexafluoroisopropyl sulfide by the BF3.NEt(3) complex. Its reactivity with respect to allyl alcohol and hexamethyldisilazane was studied. The electrophilcity of 2-(methylthio)pentafluoropropene was compared with the properties of terminal polyfluoroalkenes whose behavior in these reactions has been studied previously.

  DOI：

  10.1007/bf00699139
• 作为产物：
  描述：

  methyl 2H-hexafluoroisopropyl sulfide 在 (C2H5)3N*BF3 作用下， 反应 5.0h， 以73%的产率得到2-(methylthio)pentafluoropropene
  参考文献：
  名称：

  2-(Methylthio)pentafluoropropene

  摘要：

  2-(Methylthio) pentafluoropropene was obtained by dehydrofluorination of methyl 2H-hexafluoroisopropyl sulfide by the BF3.NEt(3) complex. Its reactivity with respect to allyl alcohol and hexamethyldisilazane was studied. The electrophilcity of 2-(methylthio)pentafluoropropene was compared with the properties of terminal polyfluoroalkenes whose behavior in these reactions has been studied previously.

  DOI：

  10.1007/bf00699139

文献信息

• Synthesis of monofluorinated compounds from methallyl chloride
  作者：G. Haufe、K. Schulze、G. Alvernhe

  DOI：10.1016/s0022-1139(00)83772-0

  日期：1991.9