| 1411934-12-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1411934-12-7
• 化学式: C₁₉H₂₁NO₂S
• 分子量: 327.447
• InChiKey: QICOJYDQBTUQJK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  哌啶 、 rac-(2R,3R)-2-[(1S)-1-iodoethyl]-3,5-dimethyl-1-(4-methylphenylsulfonyl)-2,3-dihydro-1H-indole 反应 5.0h， 以60%的产率得到(2S*,3R*)-3-methyl-1-(4-methylphenylsulfonyl)-2-vinyl-2,3-dihydro-1H-indole
  参考文献：
  名称：

  Reactions of N- and C-alkenylanilines: X. Synthesis of 2-vinyldihydroindoles from 4-methyl-2-(pent-3-en-2-yl)aniline

  摘要：

  2-(1-Iodoethyl)-3,5-dimethyl-1-(4-methylphenylsulfonyl)-2,3-dihydro-1H-indole reacted with pyridine, piperidine, N-alkylpiperidines, and dimethylformamide to give dehydrohalogenation and halogen substitution products whose ratio depended on the reagent structure. Heating of 2-(1-iodoethyl)-3,5-dimethyl-1-methylsulfonyl-2,3-dihydro-1H-indole with piperidine resulted in the formation of only dehydroiodination products.

  DOI：

  10.1134/s1070428012090096