zinc meso-trans-di(hexadecyl)tetrabenzoporphyrinate | 1033053-57-4

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: zinc meso-trans-di(hexadecyl)tetrabenzoporphyrinate
• CAS: 1033053-57-4
• 化学式: C₆₈H₈₄N₄Zn
• 分子量: 1022.83
• InChiKey: ZVKAQHHXNNWMOG-DPZSHCFESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  zinc meso-trans-di(hexadecyl)tetrabenzoporphyrinate 在 硫酸 作用下， 反应 2.0h， 以67%的产率得到5,15-dihexadecyltetrabenzoporphyrin
  参考文献：
  名称：

  5,15-dialkyl-substituted tetrabenzoporphyrins and their zinc complexes. Synthesis and spectral properties

  摘要：

  Reactions of phthalimide with capric and stearic acids gave 1-[1-(1-oxo-1H-isoindol-3-yl)nonylidene]-2,3-dihydro-1H-isoindol-3-one and 1-[1-(1-oxo-1H-isoindol-3-yl)heptadecylidene]-2,3-dihydro-1H-isoindol-3-one, respectively. The latter were heated with zinc(II) acetate to obtain zinc complexes of 5,15-dioctyl- and 5,15-dihexadecyltetrabenzoporphyrins. The same complexes were synthesized by reaction of 1-(1-oxo-1H-isoindol-3-ylmethylidene)-2,3-dihydro- 1H-isoindol-3-one with capric or stearic acid in the presence of zinc(II) oxide. The corresponding free porphyrin ligands were obtained by treatment of the metal complexes with sulfuric acid.

  DOI：

  10.1134/s1070428007090242
• 作为产物：
  描述：

  1-[1-(1-oxo-1H-isoindol-3-yl)heptadecylidene]-2,3-dihydro-1H-isoindol-3-one 在 zinc diacetate 作用下， 反应 0.5h， 以37%的产率得到zinc meso-trans-di(hexadecyl)tetrabenzoporphyrinate
  参考文献：
  名称：

  5,15-dialkyl-substituted tetrabenzoporphyrins and their zinc complexes. Synthesis and spectral properties

  摘要：

  Reactions of phthalimide with capric and stearic acids gave 1-[1-(1-oxo-1H-isoindol-3-yl)nonylidene]-2,3-dihydro-1H-isoindol-3-one and 1-[1-(1-oxo-1H-isoindol-3-yl)heptadecylidene]-2,3-dihydro-1H-isoindol-3-one, respectively. The latter were heated with zinc(II) acetate to obtain zinc complexes of 5,15-dioctyl- and 5,15-dihexadecyltetrabenzoporphyrins. The same complexes were synthesized by reaction of 1-(1-oxo-1H-isoindol-3-ylmethylidene)-2,3-dihydro- 1H-isoindol-3-one with capric or stearic acid in the presence of zinc(II) oxide. The corresponding free porphyrin ligands were obtained by treatment of the metal complexes with sulfuric acid.

  DOI：

  10.1134/s1070428007090242

文献信息

• Synthesis and Induction of Mesomorphic Properties of Tetrabenzoporphine Derivatives
  作者：V. Bykova、N. Usol'tseva、E. Kudrik、N. Galanin、G. Shaposhnikov、L. Yakubov

  DOI：10.1080/15421400802429986

  日期：2008.12.2

  Zinc complexes of meso-alkyl-substituted tetrabenzoporphines and their aza-derivatives have been. synthesized using the interaction of phthalimide or its derivatives with zinc salts of the carboxylic acids. The porphyrin-ligands were obtained on the basis of the above mentioned compounds. The spectral and mesomorphic properties of the synthesized compounds were studied.
• Sandwich complexes of yttrium, neodymium, gadolinium, and dysprosium with meso-trans-di(hexadecyl)-tetrabenzoporphyrin and phthalocyanine fragments. Synthesis and spectral properties
  作者：N. E. Galanin、G. P. Shaposhnikov

  DOI：10.1134/s1070363212040275

  日期：2012.4

  Sandwich-type asymmetric complexes of yttrium, neodymium, gadolinium, and dysprosium were synthesized by the reaction of the corresponding meso-trans-bis(hexadecyl)tetrabenzoporphyrinates with dilithium phthalocyianine. Spectral properties of these compounds were investigated.